Phenol synthesis by liquid-phase oxidation of benzene with molecular oxygen over iron-heteropoly acid

被引：40

作者：

Seo, YJ ^{[1
]}

Mukai, Y ^{[1
]}

Tagawa, T ^{[1
]}

Goto, S ^{[1
]}

机构：

[1] NAGOYA UNIV,DEPT CHEM ENGN,NAGOYA,AICHI 46401,JAPAN

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 1997年 / 120卷 / 1-3期

关键词：

heteropoly acid; oxidation of benzene; phenol synthesis; spectra;

D O I：

10.1016/S1381-1169(96)00426-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The phenol synthesis by liquid-phase oxidation of benzene with molecular oxygen over iron-heteropoly acid (HPA) system was studied. When iron salts were used with H3PW12O40, the highest activity was obtained. Spectroscopic studies showed that the state of the iron ion was changed after interaction with heteropoly acid (HPA) while the Keggin structure of HPA remained. The acidic nature of HPA activated benzene to form cationic species. Insoluble iron ion-exchanged heteropoly acid was obtained by partial ion exchange method, which also showed high activity on oxidation of benzene with molecular oxygen. The effects of reaction conditions were studied and the mechanism of deactivation was discussed. For the regeneration of catalytic activity, the addition of L-ascorbic acid as a reducing agent was suggested.

引用

页码：149 / 154

页数：6

共 11 条

[1] OXIDATION OF SALICYLATE BY THE MODEL PEROXIDASE CATALYST IRON ETHYLENEDIAMINETETRAACETATO-IRON(III) ACID [J].