Study of the free energy of the La1-xCaxMnO3 manganites based on the temperature dependence of the crystal cell volume

被引:23
作者
Tang, G. D. [1 ]
Liu, S. P.
Zhao, X.
Zhang, Y. G.
Ji, D. H.
Li, Y. F.
Qi, W. H.
Chen, W.
Hou, D. L.
机构
[1] Hebei Normal Univ, Dept Phys, Shijiazhuang 050016, Peoples R China
基金
中国国家自然科学基金;
关键词
MAGNETORESISTANCE; X=0.25;
D O I
10.1063/1.3233934
中图分类号
O59 [应用物理学];
学科分类号
摘要
A study of the free energy of the perovskite manganites was performed by fitting experimental results for the temperature dependence of the crystal cell volume using a detailed semiclassical model of the free energy. The fitted results coincide with the experimental results for the samples La1-xCaxMnO3 (x = 0.2, 0.25, 0.3, and 0.5). The free energy includes the energy corresponding to thermal vibration of the crystal lattice, the ionic cohesive energy, and additional energies produced by electrical carriers from the double exchange mechanism and the thermal activation of small polarons. (C) 2009 American Institute of Physics. [doi:10.1063/1.3233934]
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页数:3
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