Enhancement of red fluorescence and afterglow in CaTiO3: Pr3+ by addition of LU2O3

被引:66
|
作者
Zhang, Xianmin
Zhang, Jiahua
Zhang, Xia
Chen, Li
Lu, Shaozhe
Wang, Xiao-Jun
机构
[1] Chinese Acad Sci, Changchun Inst Opt Fine Mech & Phys, Key Lab Excited State Proc, Changchun 130033, Peoples R China
[2] Georgia So Univ, Dept Phys, Statesboro, GA 30460 USA
[3] Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
基金
中国国家自然科学基金;
关键词
Pr3+; red phosphor; red afterglow;
D O I
10.1016/j.jlumin.2006.01.337
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
CaTiO3:Pr3+ with addition Lu2O3 are synthesized by conventional solid-state reaction methods. It is found that the addition of Lu leads to the enhancement of red fluorescence and phosphorescence at 615 nm originating from D-1(2)-> H-3(4) transition of Pr3+ following the increase of the lifetime for the D-1(2) state. As a result, it is indicated that the non-radiative centers for the D-1(2) state are suppressed by the addition of Lu ions. The persistent time of the afterglow is observed to increase from less than 15 min to over 2 h after the addition of 5 mol% Lu2O3. A tentative mechanism of the Lu-addition effect on the optical properties is discussed. (c) 2006 Elsevier B.V. All rights reserved.
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页码:958 / 960
页数:3
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