Highly enantioselective recognition of dicarboxylic acid substrates by the control of nonlinear responses

被引：60

作者：

Ikeda, Tomohiro ^{[1
]}

Hirata, Osamu ^{[1
]}

Takeuchi, Masayuki ^{[1
]}

Shinkai, Seiji ^{[1
]}

机构：

[1] Kyushu Univ, Grad Sch Engn, Dept Chem & Biochem, Fukuoka 8190395, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 50期

关键词：

D O I：

10.1021/ja067001x

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An allosteric host, in which the molecular information of the chiral guest was precisely introduced, exhibits unconventional enantioselectivity toward the target enantiomer even under the conditions of a -20% enantiomeric excess (ee) mixture within a certain concentration window. This is effected by incorporation of the structural information of the enantiomer into the host and the utilization of multiple equilibrium. Copyright © 2006 American Chemical Society.

引用

页码：16008 / 16009

页数：2

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