The structure and stoichiometry of C-S-H

被引：471
作者：
Nonat, A [1 ]
机构：
[1] Univ Bourgogne, CNRS, UMR, Lab Rech Reactiv Solides, F-21078 Dijon, France
来源：
CEMENT AND CONCRETE RESEARCH | 2004年 / 34卷 / 09期
关键词：
calcium silicate hydrate (C-S-H); crystal size; crystal structure; spectroscopy; thermodynamic calculations;
D O I：
10.1016/j.cemconres.2004.04.035
中图分类号：
TU [建筑科学];
学科分类号：
0813 ;
摘要：
This review relates to the models describing the structural evolution of calcium silicate hydrate (C-S-H) at the crystal-chemical level as a function of composition in terms of calcium to silicon ratio. The different models are compared and discussed in the light of recent spectroscopic and microscopic data. Taking into account the structure and the morphological properties of C-S-H, a surface reaction thermodynamic model has been proposed and discussed to predict and correlate the chemical and structural evolution of C-S-H with solution chemistry. (C) 2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码：1521 / 1528
页数：8
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共 50 条
  • [1] [Anonymous], 1995, ADV CEM RES
  • [2] ARRET P, 1988, J AM CERAM SOC, V71, pC113
  • [3] The crystal structure of jennite, Ca9Si6O18(OH)6•8H2O
    Bonaccorsi, E
    Merlino, S
    Taylor, HFW
    [J]. CEMENT AND CONCRETE RESEARCH, 2004, 34 (09) : 1481 - 1488
  • [4] BRUNET F, IN PRESS J PHYS CH B
  • [5] TRICALCIUM SILICATE HYDRATE
    BUCKLE, ER
    GARD, JA
    TAYLOR, HFW
    [J]. JOURNAL OF THE CHEMICAL SOCIETY, 1958, (APR): : 1351 - &
  • [6] CARPENTER AB, 1966, AM MINERAL, V51, P56
  • [7] Si-29 MAS NMR study of the structure of calcium silicate hydrate
    Cong, XD
    Kirkpatrick, RJ
    [J]. ADVANCED CEMENT BASED MATERIALS, 1996, 3 (3-4): : 144 - 156
  • [8] COURAULT AC, 2000, SIMULATION EXPT DES
  • [9] Delville A., 1997, 2 RIL WORKSH HYDR SE, P37
  • [10] Dzombak D.A., 1990, SURFACE COMPLEXATION
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