Pursuit of Noncovalent Interactions for Strategic Site-Selective Catalysis

被引：200

作者：

Toste, F. Dean ^{[1
]}

Sigman, Matthew S. ^{[2
]}

Miller, Scott J. ^{[3
]}

机构：

[1] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA

[2] Univ Utah, Dept Chem, 315 S 1400 E, Salt Lake City, UT 84112 USA

[3] Yale Univ, Dept Chem, 225 Prospect St, New Haven, CT 06520 USA

来源：

ACCOUNTS OF CHEMICAL RESEARCH | 2017年 / 50卷 / 03期

基金：

美国国家卫生研究院;

关键词：

ANION PHASE-TRANSFER; ASYMMETRIC CATALYSIS; CHIRAL ANION; NOBEL LECTURE; TEICOPLANIN; ALCOHOLS; STEREOSELECTIVITY; FLUORINATION; DISCOVERY; OXIDATION;

D O I：

10.1021/acs.accounts.6b00613

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Selective reactions on structures of high complexity can move beyond the mind's eye and proof-of principle. Enhanced understanding of noncovalent interactions and their interdependence, revealed through analysis of multiple parameters, should accelerate the discovery of efficient reactions in highly complex molecular environments.

引用

页码：609 / 615

页数：7

共 52 条

[41] Computational Catalysis-Past, Present, and Future [J].

Thiel, Walter .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014, 53 (33) :8605-8613

[42] London Dispersion in Molecular Chemistry-Reconsidering Steric Effects [J].

Wagner, J. Philipp ;

Schreiner, Peter R. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2015, 54 (42) :12274-12296

[43]

Walsh P. J., 2008, FUNDAMENTALS ASYMMET

[44] Natural Taxanes: Developments Since 1828 [J].

Wang, Yu-Fang ;

Shi, Qing-Wen ;

Dong, Mei ;

Kiyota, Hiromasa ;

Gu, Yu-Cheng ;

Cong, Bin .

CHEMICAL REVIEWS, 2011, 111 (12) :7652-7709

[45] Adding Aliphatic C-H Bond Oxidations to Synthesis [J].

White, M. Christina .

SCIENCE, 2012, 335 (6070) :807-809

[46] Complexity in chemistry [J].

Whitesides, GM ;

Ismagilov, RF .

SCIENCE, 1999, 284 (5411) :89-92

[47] Electronic tuning of site-selectivity [J].

Wilcock, Brandon C. ;

Uno, Brice E. ;

Bromann, Gretchen L. ;

Clark, Matthew J. ;

Anderson, Thomas M. ;

Burke, Martin D. .

NATURE CHEMISTRY, 2012, 4 (12) :996-1003

[48] Two-Phase Synthesis of (-)-Taxuyunnanine D [J].

Wilde, Nathan C. ;

Isomura, Minetaka ;

Mendoza, Abraham ;

Baran, Phil S. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (13) :4909-4912

[49] A combination of directing groups and chiral anion phase-transfer catalysis for enantioselective fluorination of alkenes [J].

Wu, Jeffrey ;

Wang, Yi-Ming ;

Drljevic, Amela ;

Rauniyar, Vivek ;

Phipps, Robert J. ;

Toste, F. Dean .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2013, 110 (34) :13729-13733

[50] Development and Analysis of a Pd(0)-Catalyzed Enantioselective 1,1-Diarylation of Acrylates Enabled by Chiral Anion Phase Transfer [J].

Yamamoto, Eiji ;

Hilton, Margaret J. ;

Orlandi, Manuel ;

Saini, Vaneet ;

Toste, F. Dean ;

Sigman, Matthew S. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2016, 138 (49) :15877-15880

← 1 2 3 4 5 6 →