Pursuit of Noncovalent Interactions for Strategic Site-Selective Catalysis

被引：200

作者：

Toste, F. Dean ^{[1
]}

Sigman, Matthew S. ^{[2
]}

Miller, Scott J. ^{[3
]}

机构：

[1] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA

[2] Univ Utah, Dept Chem, 315 S 1400 E, Salt Lake City, UT 84112 USA

[3] Yale Univ, Dept Chem, 225 Prospect St, New Haven, CT 06520 USA

来源：

ACCOUNTS OF CHEMICAL RESEARCH | 2017年 / 50卷 / 03期

基金：

美国国家卫生研究院;

关键词：

ANION PHASE-TRANSFER; ASYMMETRIC CATALYSIS; CHIRAL ANION; NOBEL LECTURE; TEICOPLANIN; ALCOHOLS; STEREOSELECTIVITY; FLUORINATION; DISCOVERY; OXIDATION;

D O I：

10.1021/acs.accounts.6b00613

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Selective reactions on structures of high complexity can move beyond the mind's eye and proof-of principle. Enhanced understanding of noncovalent interactions and their interdependence, revealed through analysis of multiple parameters, should accelerate the discovery of efficient reactions in highly complex molecular environments.

引用

页码：609 / 615

页数：7

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