Density, Viscosity, and Derivative Properties of Diethylene Glycol Monoethyl Ether Under High Pressure and Temperature

被引:16
|
作者
Lifi, Mohamed [1 ,2 ]
Bazile, Jean Patrick [1 ]
Munoz-Rujas, Natalia [2 ]
Galliero, Guillaume [1 ]
Aguilar, Fernando [2 ]
Daridon, Jean Luc [1 ]
机构
[1] Univ Pau, Lab Fluides Complexes & Leurs Reservoirs, UMR5150, CNRS TOTAL,E2S UPPA, BP 1155, F-64013 Pau, France
[2] Univ Burgos, Dept Ingn Electromecan, Escuela Politecn Super, E-09006 Burgos, Spain
来源
JOURNAL OF CHEMICAL AND ENGINEERING DATA | 2021年 / 66卷 / 03期
关键词
EXCESS MOLAR VOLUMES; EQUATION-OF-STATE; ORGANIC-SOLVENT MIXTURES; PERTURBED-CHAIN SAFT; DIRECTIONAL ATTRACTIVE FORCES; LIQUID-LIQUID EQUILIBRIA; N-ALKOXYETHANOLS; BINARY-MIXTURES; THERMODYNAMIC PROPERTIES; 140; MPA;
D O I
10.1021/acs.jced.0c01055
中图分类号
O414.1 [热力学];
学科分类号
摘要
The measurement of densities (rho) of the pure component diethylene glycol monoethyl ether (2-(2-ethoxyethoxy)-ethanol) has been carried out using a vibrating-tube densimeter (Anton Paar DMA HPM) along temperatures varying from 293.15 to 353.15 K and pressures from 0.1 to 70 MPa with an expanded uncertainty of 0.5 kg.m(-3). High-pressure dynamic viscosity (eta) measurements were performed with a falling body viscometer at pressure values up to 70 MPa and within a temperature range from 293.15 to 353.15 K with an expanded relative uncertainty of 0.03 eta. The dynamic viscosity was determined at 0.1 MPa, thanks to an Ubbelohde capillary viscometer, with an expanded relative uncertainty smaller than 0.01 eta. Density experiments were adjusted using a Tait-like equation and modeled by employing the perturbed-chain statistical associating fluid equation of state (EoS). Moreover, high-pressure dynamic viscosity experimental data were correlated using the Vogel-Fulcher-Tammann (VFT) equation.
引用
收藏
页码:1457 / 1465
页数:9
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