Hydrogen-bonded boron imidazolate frameworks

被引:13
作者
Zhang, Jian [1 ]
Wu, Tao [2 ]
Feng, Pingyun [2 ]
Bu, Xianhui [1 ]
机构
[1] Calif State Univ Long Beach, Dept Chem & Biochem, Long Beach, CA 90840 USA
[2] Univ Calif Riverside, Dept Chem, Riverside, CA 92521 USA
基金
美国国家科学基金会;
关键词
METAL-ORGANIC FRAMEWORKS; CRYSTAL-STRUCTURES;
D O I
10.1039/b924633a
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The research on tetrahedral imidazolate frameworks takes on a new direction into the supramolecular area through the synthesis of three hydrogen-bonded boron imidazolate (B[im](4)(-)) frameworks (HBIFs) that show distinct three- and two-dimensional supramolecular architectures: (1) the ionic diamond net containing the first reported Li+ complex with ethylene glycol, (2) four-connected double-layers built from a new neutral Li(tea)B(im)(4) (tea = triethanolamine) complex, and (3) three- connected (6,3) layer of H3O center dot BH(eim)(3).
引用
收藏
页码:1702 / 1704
页数:3
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