Spectroscopic Characterization and Reactivity of Triplet and Quintet Iron(IV) Oxo Complexes in the Gas Phase

被引：30

作者：

Andris, Erik ^{[1
]}

Jasik, Juraj ^{[1
]}

Gomez, Laura ^{[2
,3
,4
]}

Costas, Miquel ^{[2
,3
]}

Roithova, Jana ^{[1
]}

机构：

[1] Charles Univ Prague, Fac Sci, Dept Organ Chem, Hlavova 2030-8, Prague 12843 2, Czech Republic

[2] Univ Girona, Dept Quim, Campus Montilivi, Girona 17071, Spain

[3] Univ Girona, Inst Computat Chem & Catalysis IQCC, Campus Montilivi, Girona 17071, Spain

[4] Univ Girona Parc Cient & Tecnol, STR, Girona 17003, Spain

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2016年 / 55卷 / 11期

基金：

欧洲研究理事会;

关键词：

C-H activation; IR spectroscopy; iron complexes; mass spectrometry; spin state; EXCHANGE-ENHANCED REACTIVITY; ION-MOLECULE REACTIONS; NONHEME; ACTIVATION; ENZYMES; CATION;

D O I：

10.1002/anie.201511374

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Closely structurally related triplet and quintet iron(IV) oxo complexes with a tetradentate aminopyridine ligand were generated in the gas phase, spectroscopically characterized, and their reactivities in hydrogen-transfer and oxygen-transfer reactions were compared. The spin states were unambiguously assigned based on helium tagging infrared photodissociation (IRPD) spectra of the mass-selected iron complexes. It is shown that the stretching vibrations of the nitrate counterion can be used as a spectral marker of the central iron spin state.

引用

页码：3637 / 3641

页数：5

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