Silver-catalyzed direct selenylation of terminal alkynes through C-H bond functionalization

被引：24

作者：

Xavier, Mauricio C. D. F. ^{[1
]}

Goldani, Bruna ^{[1
]}

Schumacher, Ricardo F. ^{[1
]}

Perin, Gelson ^{[1
]}

Schneider, Paulo Henrique ^{[2
]}

Alves, Diego ^{[1
]}

机构：

[1] Univ Fed Pelotas, UFPel, CCQFA, Lab Sintese Organ Limpa,LASOL, POB 354, BR-35496010 Pelotas, RS, Brazil

[2] Univ Fed Rio Grande do Sul, Inst Quim, UFRGS, Porto Alegre, RS, Brazil

来源：

MOLECULAR CATALYSIS | 2017年 / 427卷

关键词：

C-H Functionalization; Alkynes; Silver; Selenium; Catalysis; HIGHLY EFFICIENT; CHALCOGENIDES SELENIDES; CYCLOADDITION REACTIONS; SYNTHETIC ROUTE; ACTIVATION; TELLURIDES; DICHALCOGENIDES; CYCLIZATION; ACETYLENES; WATER;

D O I：

10.1016/j.molcata.2016.11.033

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We described herein the use of a silver catalyst in the selenylation of terminal alkynes by direct C-H functionalization. These reactions were performed under mild conditions, reacting a range of terminal alkynes with different diorganyl diselenides using AgNO3 (10 mol-%) as catalyst in CH2Cl2 at 25 degrees C under air atmosphere. This is an efficient and general cross-coupling reaction and was performed with alkynes and diorganyl diselenides bearing electron-withdrawing and electron-donating groups affording the corresponding selanylalkynes in good to excellent yields. (C) 2016 Published by Elsevier B.V.

引用

页码：73 / 79

页数：7

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