Effect of Precipitation Methods on Catalytic Activity of Ru/CeO2 Catalyst for Ammonia Synthesis

被引:0
|
作者
Luo Xiaojun [1 ]
Wang Rong [1 ]
Lin Jianxin [1 ]
Wei Kemei [1 ]
机构
[1] Fuzhou Univ, Natl Res Ctr Chem Fertilizer Catalysts, Fuzhou 350002, Fujian, Peoples R China
关键词
precipitation method; ammonia synthesis; cerium dioxide; ruthenium; co-precipitation; deposition-precipitation; WATER-GAS SHIFT; RUTHENIUM CATALYSTS; CEO2; RU; SUPPORT; PROMOTERS; STABILITY; CHLORINE; BEHAVIOR; ALUMINA;
D O I
暂无
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
The Ru/CeO2 catalyst was prepared by precipitation methods, including normal precipitation, reverse precipitation, parallel flow precipitation, and deposition-precipitation. The obtained catalysts were characterized by N-2 adsorption-desorption, X-ray diffraction, H-2 temperature-programmed reduction, CO chemisorption, and X-ray fluorescence spectroscopy. The results showed that the ammonia synthesis activity of the Ru/CeO2 catalyst prepared by normal precipitation was 11.9% at 10 MPa, 10000 h(-1), and 450 degrees C, which was higher than those obtained by other methods. The residual chloride content in this catalyst was much lower and its cerium was easier to be reduced. Thus the activity of the catalyst prepared using normal precipitation was high.
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页码:1125 / 1130
页数:6
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