Epoxidized Jatropha Oil as a Sustainable Plasticizer to Poly(lactic Acid)

被引:44
作者
Chieng, Buong Woei [1 ,2 ]
Ibrahim, Nor Azowa [1 ,2 ]
Then, Yoon Yee [3 ]
Loo, Yuet Ying [4 ]
机构
[1] Univ Putra Malaysia, Dept Chem, Fac Sci, Upm Serdang 43400, Selangor, Malaysia
[2] Univ Putra Malaysia, Mat Proc & Technol Lab, Inst Adv Technol, Upm Serdang 43400, Selangor, Malaysia
[3] Int Med Univ, Dept Pharmaceut Chem, Sch Pharm, 126,Jalan Jalil Perkasa 19, Kuala Lumpur 57000, Malaysia
[4] Univ Putra Malaysia, Fac Food Sci & Technol, Dept Food Sci, Upm Serdang 43400, Selangor, Malaysia
关键词
jatropha oil; epoxidized oil; plasticizer; poly(lactic acid); PALM OIL; MORPHOLOGY PROPERTIES; SOYBEAN OIL; BLEND; FILMS;
D O I
10.3390/polym9060204
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
A renewable resource, epoxidized jatropha oil (EJO), was used as a green plasticizer and added to poly(lactic acid) (PLA). EJO was compounded into PLA at different contents. The addition of 3 wt % EJO to the PLA demonstrates significant improvement in flexibility, which leads to a percentage increase of about 7000% in elongation at break. This tensile result was confirmed by surface morphology analysis with clear proof of plastic deformation in EJO-plasticized PLA. EJO imparts a good heat stabilization effect. Thermal stability of PLA was enhanced upon addition of EJO, which is due to their good interaction and plasticizer dispersion within the PLA matrix. This EJO-plasticized PLA has wide applications in various industries, such as packaging of food and non-food products.
引用
收藏
页数:10
相关论文
共 20 条
[1]   Properties of epoxidized palm oil plasticized polytlactic acid [J].
Al-Mulla, Emad A. Jaffar ;
Yunus, Wan Md. Zin Wan ;
Ibrahim, Nor Azowa Bt ;
Ab Rahman, Mohd Zaki .
JOURNAL OF MATERIALS SCIENCE, 2010, 45 (07) :1942-1946
[2]   Characterization and ageing study of poly(lactic acid) films plasticized with oligomeric lactic acid [J].
Burgos, Nuria ;
Martino, Veronica P. ;
Jimenez, Alfonso .
POLYMER DEGRADATION AND STABILITY, 2013, 98 (02) :651-658
[3]   Mechanical, thermal, and morphology properties of poly(lactic acid) plasticized with poly(ethylene glycol) and epoxidized palm oil hybrid plasticizer [J].
Chieng, Buong Woei ;
Ibrahim, Nor Azowa ;
Then, Yoon Yee ;
Loo, Yuet Ying .
POLYMER ENGINEERING AND SCIENCE, 2016, 56 (10) :1169-1174
[4]   Reinforcement of graphene nanoplatelets on plasticized poly(lactic acid) nanocomposites: Mechanical, thermal, morphology, and antibacterial properties [J].
Chieng, Buong Woei ;
Ibrahim, Nor Azowa ;
Yunus, Wan Md Zin Wan ;
Hussein, Mohd Zobir ;
Then, Yoon Yee ;
Loo, Yuet Ying .
JOURNAL OF APPLIED POLYMER SCIENCE, 2015, 132 (11)
[5]   Epoxidized Vegetable Oils Plasticized Poly(lactic acid) Biocomposites: Mechanical, Thermal and Morphology Properties [J].
Chieng, Buong Woei ;
Ibrahim, Nor Azowa ;
Then, Yoon Yee ;
Loo, Yuet Ying .
MOLECULES, 2014, 19 (10) :16024-16038
[6]   Poly(lactic acid)/Poly(ethylene glycol) Polymer Nanocomposites: Effects of Graphene Nanoplatelets [J].
Chieng, Buong Woei ;
Ibrahim, Nor Azowa ;
Yunus, Wan Md Zin Wan ;
Hussein, Mohd Zobir .
POLYMERS, 2014, 6 (01) :93-104
[7]   Plasticized Poly(lactic acid) with Low Molecular Weight Poly(ethylene glycol): Mechanical, Thermal, and Morphology Properties [J].
Chieng, Buong Woei ;
Ibrahim, Nor Azowa ;
Yunus, Wan Md Zin Wan ;
Hussein, Mohd Zobir .
JOURNAL OF APPLIED POLYMER SCIENCE, 2013, 130 (06) :4576-4580
[8]   Emerging sustainable technology for epoxidation directed toward plant oil-based plasticizers [J].
Chua, Seong-Chea ;
Xu, Xuebing ;
Guo, Zheng .
PROCESS BIOCHEMISTRY, 2012, 47 (10) :1439-1451
[9]   Synthesis and properties of highly branched Jatropha curcas L. oil derivatives [J].
Daniel, Louis ;
Ardiyanti, Agnes R. ;
Schuur, Boelo ;
Manurung, Robert ;
Broekhuis, Antonius A. ;
Heeres, Hero J. .
EUROPEAN JOURNAL OF LIPID SCIENCE AND TECHNOLOGY, 2011, 113 (01) :18-30
[10]   Plasticizing effect of biobased epoxidized fatty acid esters on mechanical and thermal properties of poly(lactic acid) [J].
Ferri, J. M. ;
Samper, M. D. ;
Garcia-Sanoguera, D. ;
Reig, M. J. ;
Fenollar, O. ;
Balart, R. .
JOURNAL OF MATERIALS SCIENCE, 2016, 51 (11) :5356-5366