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Catalytic Transformation of Lignocellulose into Chemicals and Fuel Products in Ionic Liquids
被引:804
作者:
Zhang, Zhanrong
[1
]
Song, Jinliang
[1
]
Han, Buxing
[1
]
机构:
[1] Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, Key Lab Colloid & Interface & Thermodynam, Beijing 100190, Peoples R China
基金:
中国国家自然科学基金;
关键词:
ONE-POT CELLULOSE;
AEROBIC ALCOHOL OXIDATION;
LIGNIN MODEL-COMPOUND;
SOLID ACID;
LEVULINIC ACID;
LACTIC-ACID;
HYDROLYTIC HYDROGENATION;
SELECTIVE CONVERSION;
EFFICIENT CONVERSION;
KRAFT LIGNIN;
D O I:
10.1021/acs.chemrev.6b00457
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
Innovative valorization of naturally abundant and renewable lignocellulosic biomass is of great importance in the pursuit of a sustainable future and biobased economy. Ionic liquids (ILs) as an important kind of green solvents and functional fluids have attracted significant attention for the catalytic transformation of lignocellulosic feedstocks into a diverse range of products. Taking advantage of some unique properties of ILs with different functions, the catalytic transformation processes can be carried out more efficiently and potentially with lower environmental impacts. Also, a new product portfolio may be derived from catalytic systems with ILs as media. This review focuses on the catalytic chemical conversion of lignocellulose and its primary ingredients (i.e., cellulose, hemicellulose, and lignin) into value-added chemicals and fuel products using ILs as the reaction media. An outlook is provided at the end of this review to highlight the challenges and opportunities associated with this interesting and important area.
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页码:6834 / 6880
页数:47
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