Combustion Characteristics and Synergistic Effect of Halogen-Free Flame-Retarded EVA/Hydrotalcite Blends with Expandable Graphite and Fumed Silica

被引:20
作者
Du, Longchao [1 ,2 ]
Zhang, Yuchuan [1 ]
Yuan, Xiaoyou [1 ]
Chen, Jinyang [2 ]
机构
[1] Anhui Univ, Fac Chem & Chem Engn, Key Lab Environm Friendly Polymer Mat Anhui Prov, Hefei 230039, Anhui, Peoples R China
[2] Zhongding Sealing Parts Co Ltd, Ningguo, Anhui, Peoples R China
关键词
EVA; Flammability; Hydrotalcite; Synergistic effect; LAYERED DOUBLE HYDROXIDES; MAGNESIUM-HYDROXIDE; STRUCTURAL-CHARACTERIZATION; PHOSPHORUS; HYDROTALCITE; EXCHANGE;
D O I
10.1080/03602550903092500
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The synergistic effect of hydrotalcite with EG and fumed silica in halogen-free, flame-retardant EVA blends have been studied by limiting oxygen index (LOI), UL-94 test, cone calorimeter test (CCT), and TGA. The EG is a very effective synergist in raising LOI and reducing the heat release rate (HRR) and SEA of the blends. The UL 94 tests show that samples with 2-15 wt% EG can exceed the V-0 rate. The CCT data show that 15 wt% higher expansible ratio EG shows maximum decreases for the pk-HRR and av-SEA values of the EVA/hydrotalcite blends. The fumed silica have no obvious synergistic effects with hydrotalcite.
引用
收藏
页码:1002 / 1007
页数:6
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