Development of Ti-Mo alloys for biomedical applications: Microstructure and electrochemical characterization

被引:168
作者
Oliveira, Nilson T. C. [1 ]
Aleixo, Giorgia
Caram, Rubens
Guastaldi, Antonio C.
机构
[1] UNESP, Inst Quim, Grp Biomat, Araraquara, SP, Brazil
[2] Univ Estadual Campinas, FEM, Lab Met Fis & Solidificacao, Campinas, SP, Brazil
来源
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING | 2007年 / 452卷
基金
巴西圣保罗研究基金会;
关键词
Ti-Mo alloys; biocompatible alloys; biomedical titanium alloys; corrosion; microstructure;
D O I
10.1016/j.msea.2006.11.061
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Ti-Mo alloys from 4 to 20 Mo wt.% were arc-melted. Their compositions and surfaces were analyzed by EDX, XRF and SEM. The Mo mapping shows a homogeneous distribution for all alloys. The XRD analysis showed that the crystal structure of the alloys is sensitive to the Mo concentration; a mixture of the hexagonal alpha' and orthorhombic alpha '' phases was observed for the Ti-4Mo alloy, and the alpha '' phase is observed almost exclusively when the concentration of Mo added to the Ti reaches 6%. A significant retention of the beta phase is observed for the alloy containing 10% Mo, while at higher Mo concentrations (15% and 20%), retention of phase beta is only verified. Preliminary electrochemical studies have indicated a valve-metal behavior and good corrosion resistance in aerated Ringer solution for all alloys. (c) 2006 Published by Elsevier B.V.
引用
收藏
页码:727 / 731
页数:5
相关论文
共 26 条
[1]  
*ASM INT, 1996, BIN ALL PHAS DIAGR, V3
[2]  
Bania P, 1993, BETA TITANIUM ALLOYS
[3]  
Branemark P I., 1997, Osseointegrated implants in the treatment of the edentulous jaw. Experience from a 10-year period
[4]  
Czarnowska E, 1999, J MATER PROCESS TECH, V93, P190
[5]   THE ANODIC BEHAVIOR OF NIOBIUM .2. GENERAL EXPERIMENTAL ELECTROCHEMICAL ASPECTS [J].
DALKAINE, CV ;
DESOUZA, LMM ;
NART, FC .
CORROSION SCIENCE, 1993, 34 (01) :117-127
[6]  
DAVIS R, 1979, J MATER SCI, V14, P22
[7]   Study of the corrosion behavior of titanium and some of its alloys for biomedical and dental implant applications [J].
González, JEG ;
Mirza-Rosca, JC .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1999, 471 (02) :109-115
[8]  
GUASTALDI AC, 2003, METALURGIA MAT, V59, P442
[9]   Surface reconstruction associated with α precipitation in a Ti-Mo alloy [J].
Guo, H ;
Enomoto, M .
SCRIPTA MATERIALIA, 2006, 54 (07) :1409-1413
[10]   Structure and properties of cast binary Ti-Mo alloys [J].
Ho, WF ;
Ju, CP ;
Lin, JHC .
BIOMATERIALS, 1999, 20 (22) :2115-2122