Synthesis and characterization of Fe2O3/SiO2 nanocomposites

被引：37

作者：

Bogatyrev, V. M. ^{[1
]}

Gun'ko, V. M. ^{[1
]}

Galaburda, M. V. ^{[1
]}

Borysenko, M. V. ^{[1
]}

Pokrovskiy, V. A. ^{[1
]}

Oranska, O. I. ^{[1
]}

Polshin, E. V. ^{[2
]}

Korduban, O. M. ^{[2
]}

Leboda, R. ^{[3
]}

Skubiszewska-Zieba, J. ^{[3
]}

机构：

[1] Natl Acad Sci Ukraine, Chuiko Inst Surface Chem, UA-03164 Kiev, Ukraine

[2] Kurdyumov Inst Met Phys, UA-03142 Kiev, Ukraine

[3] Marie Curie Sklodowska Univ, Fac Chem, PL-20031 Lublin, Poland

来源：

JOURNAL OF COLLOID AND INTERFACE SCIENCE | 2009年 / 338卷 / 02期

关键词：

Nanosilica; Iron oxide deposits; Fe2O3/SiO2; nanocomposite; Phase composition; Structural characteristics; Electronic structure; SILICA; NANOPARTICLES; SURFACE; SPECTROSCOPY; TEMPERATURE; ADSORPTION; HEMATITE; SYSTEM; MATRIX; FE3O4;

D O I：

10.1016/j.jcis.2009.06.044

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Fe2O3/SiO2 nanocomposites based on fumed silica A-300 (S-BET = 337 m(2)/g) with iron oxide deposits at different content were synthesized using Fe(III) acetylacetonate (Fe(acac)(3)) dissolved in isopropyl alcohol or carbon tetrachloride for impregnation of the nanosilica powder at different amounts of Fe(acac)(3) then oxidized in air at 400-900 degrees C. Samples with Fe(acac)(3) adsorbed onto nanosilica and samples with Fe2O3/SiO2 including 6-17 wt% of Fe2O3 were investigated using XRD, XPS, TG/DTA, TPD MS, FTIR, AFM, nitrogen adsorption, Mossbauer spectroscopy, and quantum chemistry methods. The structural characteristics and phase composition of Fe2O3 deposits depend on reaction conditions, solvent type, content of grafted iron oxide, and post-reaction treatments. The iron oxide deposits on A-300 (impregnated by the Fe(acac)(3) solution in isopropanol) treated at 500-600 degrees C include several phases characterized by different nanoparticle size distributions; however, in the case of impregnation of A-300 by the Fe(acac)(3) solution in carbon tetrachloride only alpha-Fe2O3 phase is formed in addition to amorphous Fe2O3. The Fe2O3/SiO2 materials remain loose (similar to the A-300 matrix) at the bulk density of 0.12-0.15 g/cm(3) and SBET = 265-310 m(2)/g. (C) 2009 Elsevier Inc. All rights reserved.

引用

页码：376 / 388

页数：13

共 42 条

[1] ORIENTED OVERGROWTH OF ACICULAR MAGHEMITE CRYSTALS ON QUARTZ [J].

ABREU, MM ;

FIGUEIREDO, MO ;

WAERENBORGH, JC ;

CABRAL, JMP .

CLAY MINERALS, 1988, 23 (04) :357-365

[2]

[Anonymous], 2016, GAUSSIAN 16 REV B01

[3] Synthesis of Fe2O3 concentrations and sintering temperature on FTIR and magnetic susceptibility measured from 4 to 300 K of monolith silica gel prepared by sol-gel technique [J].

Battisha, I. K. ;

Afifya, H. H. ;

Ibrahim, M. .

JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 2006, 306 (02) :211-217

[4] Magnetically textured γ-Fe2O3 nanoparticles in a silica gel matrix:: Optical and magneto-optical properties [J].

Bentivegna, F ;

Nyvlt, M ;

Ferré, J ;

Jamet, JP ;

Brun, A ;

Visnovsky, S ;

Urban, R .

JOURNAL OF APPLIED PHYSICS, 1999, 85 (04) :2270-2278

[5]

Bourlinos A, 2001, ADV MATER, V13, P289, DOI 10.1002/1521-4095(200102)13:4<289::AID-ADMA289>3.0.CO

[6]

2-U

[7] Iron acetylacetonate complex anchored on silica xerogel polymer [J].

Brasil, MC ;

Benvenutti, EV ;

Gregório, JR ;

Gerbase, AE .

REACTIVE & FUNCTIONAL POLYMERS, 2005, 63 (02) :135-141

[8]

Briggs D., 1983, Practical Surface Analysis: by Auger and X-ray Photoelectron Spectroscopy

[9]

Cranshaw T. E., 1985, MOSSBAUER SPECTROSCO

[10] Formation of gamma-Fe2O3 isolated nanoparticles in a silica matrix [J].

delMonte, F ;

Morales, MP ;

Levy, D ;

Fernandez, A ;

Ocana, M ;

Roig, A ;

Molins, E ;

OGrady, K ;

Serna, CJ .

LANGMUIR, 1997, 13 (14) :3627-3634

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