Terminal ligand effect on the structure variation of Copper(II) complexes

被引：15

作者：

Zhai, Bin ^{[1
]}

Shen, Wei-Zheng ^{[1
]}

Chen, Xiao-Yan ^{[1
]}

Song, Hai-Bin ^{[1
]}

Shi, Wei ^{[1
]}

Cheng, Peng ^{[1
]}

机构：

[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2006年 / 9卷 / 12期

基金：

中国国家自然科学基金;

关键词：

bis(3,5-dimethylpyrazolyl)methane; tris(pyrazolyl)methane; terephthalic acid; copper(II) complex; crystal structure;

D O I：

10.1016/j.inoche.2006.08.002

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two copper(II)-poly(pyrazolyl)methane complexes [Cu-2(bpm)(4)(ta)](ClO4)(2) center dot 2H(2)O 1 and {[Cu-2(tpm)(2)(ta)(2)] center dot H2O}(n) 2 (bpm = bis(3,5-dimethylpyrazolyl)methane, tpm = tris(pyrazolyl)methane, H(2)ta = terephthalic acid) were synthesized and characterized by elemental analysis: FT-IR and UV-vis spectra. 1 is a binuclear complex, while 2 exhibits as a 1D zigzag coordination polymer. (C) 2006 Elsevier B.N. All rights reserved.

引用

页码：1293 / 1296

页数：4

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