Layered Perovskite Oxychloride Bi4NbO8Cl: A Stable Visible Light Responsive Photocatalyst for Water Splitting

被引：390

作者：

Fujito, Hironori ^{[1
]}

Kunioku, Hironobu ^{[1
]}

Kato, Daichi ^{[1
]}

Suzuki, Hajime ^{[1
]}

Higashi, Masanobu ^{[1
]}

Kageyama, Hiroshi ^{[1
,2
]}

Abe, Ryu ^{[1
,2
]}

机构：

[1] Kyoto Univ, Grad Sch Engn, Dept Energy & Hydrocarbon Chem, Nishikyo Ku, Kyoto 6158510, Japan

[2] Japan Sci & Technol Agcy JST, CREST, Kawaguchi, Saitama 3320012, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2016年 / 138卷 / 07期

基金：

日本科学技术振兴机构;

关键词：

HYDROGEN-PRODUCTION; OXYNITRIDE; O-2; PHOTOANODE; BIOCL; FABRICATION; SM2TI2S2O5; REDUCTION; LATIO2N; H-2;

D O I：

10.1021/jacs.5b11191

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Mixed anion compounds are expected to be a photocatalyst for visible light-induced water splitting, but the available materials have been almost limited to oxynitrides. Here, we show that an oxychrolide Bi4NbO8Cl, a single layer Sillen-Aurivillius perovskite, is a stable and efficient O-2-evolving photocatalyst under visible light, enabling a Z-scheme overall water splitting by coupling with a H-2-evolving photocatalyst (Rh-doped SrTiO3). It is found that the valence band maximum of Bi(4)NbO(8)Clis unusually high owing to highly dispersive O-2p orbitals (not Cl-3p orbitals), affording the narrow band gap and possibly the stability against water oxidation. This study suggests that a family of Sillen-Aurivillius perovskite oxyhalides is a promising system to allow a versatile band level tuning for establishing efficient and stable water splitting under visible light.

引用

页码：2082 / 2085

页数：4

共 32 条

[1] Recent progress on photocatalytic and photoelectrochemical water splitting under visible light irradiation [J].

Abe, Ryu .

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY C-PHOTOCHEMISTRY REVIEWS, 2010, 11 (04) :179-209

[2] Facile Fabrication of an Efficient Oxynitride TaON Photoanode for Overall Water Splitting into H2 and O2 under Visible Light Irradiation [J].

Abe, Ryu ;

Higashi, Masanobu ;

Domen, Kazunari .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (34) :11828-11829

[3]

BUHLER N, 1984, J PHYS CHEM-US, V88, P3261, DOI 10.1021/j150659a025

[4] First principles methods using CASTEP [J].

Clark, SJ ;

Segall, MD ;

Pickard, CJ ;

Hasnip, PJ ;

Probert, MJ ;

Refson, K ;

Payne, MC .

ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 2005, 220 (5-6) :567-570

[5] VISIBLE-LIGHT-INDUCED O-2 GENERATION FROM AQUEOUS DISPERSIONS OF WO3 [J].

ERBS, W ;

DESILVESTRO, J ;

BORGARELLO, E ;

GRATZEL, M .

JOURNAL OF PHYSICAL CHEMISTRY, 1984, 88 (18) :4001-4006

[6] Hydrogen production by molecular photocatalysis [J].

Esswein, Arthur J. ;

Nocera, Daniel G. .

CHEMICAL REVIEWS, 2007, 107 (10) :4022-4047

[7] A novel Bi-based oxybromide Bi4NbO8Br: Synthesis, characterization and visible-light-active photocatalytic activity [J].

He, Ying ;

Zhang, Yihe ;

Huang, Hongwei ;

Tian, Na ;

Guo, Yuxi ;

Luo, Yi .

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2014, 462 :131-136

[8] Fabrication of an Efficient BaTaO2N Photoanode Harvesting a Wide Range of Visible Light for Water Splitting [J].

Higashi, Masanobu ;

Domen, Kazunari ;

Abe, Ryu .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (28) :10238-10241

[9] Oxysulfide Sm2Ti2S2O5 as a stable photocatalyst for water oxidation and reduction under visible light irradiation (λ ≤ 650 nm) [J].

Ishikawa, A ;

Takata, T ;

Kondo, JN ;

Hara, M ;

Kobayashi, H ;

Domen, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (45) :13547-13553

[10] One-pot solvothermal synthesis of S doped BiOCl for solar water oxidation [J].

Jiang, Zaiyong ;

Liu, Yuanyuan ;

Jing, Tao ;

Huang, Baibiao ;

Wang, Zeyan ;

Zhang, Xiaoyang ;

Qin, Xiaoyan ;

Dai, Ying .

RSC ADVANCES, 2015, 5 (58) :47261-47264

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