New approach to the synthesis of benzo[e][1,2,3,4]tetrazine 1,3-dioxides

被引:28
|
作者
Frumkin, AE [1 ]
Churakov, AM [1 ]
Strelenko, YA [1 ]
Tartakovsky, VA [1 ]
机构
[1] Russian Acad Sci, ND Zelinskii Organ Chem Inst, Moscow 117913, Russia
关键词
aromatic N-nitroamines; benzo[e][1,2,3,4]tetrazine 1,3-dioxides; azoxy compounds; formation of the N-N bond;
D O I
10.1007/BF02494779
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new approach to the synthesis of benzo[e][1,2,3,4]tetrazine 1,3-dioxides involves the treatment of N-nitroanilines containing an ortho-(tert-butyl-NNO-azoxy) group with phosphoric anhydride or phosphorus pentachloride. The reaction is supposed to proceed through an intermediate diazonium oxide cation.
引用
收藏
页码:482 / 486
页数:5
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