Cyanide-bridged oligonuclear complex features and attractions

被引：183
作者：
Vahrenkamp, H
Geiss, A
Richardson, GN
机构：
[1] Institut für Anorganische und Analytische Chemie, Universität Freiburg, D-79104 Freiburg
来源：
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1997年 / 20期
关键词：
D O I：
10.1039/a703504g
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The synthetic and structural chemistry as well as some physical and chemical properties of cyanide-bridged complexes containing two or more metal building blocks are discussed. Emphasis is laid on molecular shape and design and their consequences, including the effects of cyanide-isocyanide isomerism. Redox phenomena and molecular magnetism have been dealt with in relation to electronic communication across the cyanide bridges and metal-metal charge transfer. Long-range interactions between remote metal centers are discussed, and the few cases where they lead to remote chemical reactions are listed.
引用
收藏
页码：3643 / 3651
页数：9
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