Phosphine-substituted porphyrins as supramolecular building blocks

被引：38

作者：

Darling, SL ^{[1
]}

Stulz, E ^{[1
]}

Feeder, N ^{[1
]}

Bampos, N ^{[1
]}

Sanders, JKM ^{[1
]}

机构：

[1] Univ Cambridge, Cambridge Ctr Mol Recognit, Chem Lab, Cambridge CB2 1EW, England

来源：

NEW JOURNAL OF CHEMISTRY | 2000年 / 24卷 / 05期

关键词：

D O I：

10.1039/b000482k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A route to alkyne-phosphine-substituted metalloporphyrins is presented. The X-ray structure of the methanol adduct of a diphenylphosphine Zn(II) porphyrin reveals solid state dimerisation accompanied by proton transfer from coordinated methanol to phosphine in a process reminiscent of carbonic anhydrase, The ability of the phosphine-substituted porphyrins to form non-covalent arrays with a Ru(II) porphyrin was explored using H-1/P-31 NMR and UV/vis spectroscopy as well as MALDI-TOF mass spectrometry.

引用

页码：261 / 264

页数：4

共 19 条

[1] PREPARATION AND CHARACTERIZATION OF SOME RUTHENIUM(II) PORPHYRINS CONTAINING TERTIARY PHOSPHINE AXIAL LIGANDS, INCLUDING THE CRYSTAL-STRUCTURE OF (OCTAETHYLPORPHINATO)BIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II)
ARIEL, S
DOLPHIN, D
DOMAZETIS, G
JAMES, BR
LEUNG, TW
RETTIG, SJ
TROTTER, J
WILLIAMS, GM
[J]. CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1984, 62 (04): : 755 - 762
[2] Formation of 1,11-bis(pendant donor)-cyclam derivatives via the formamidinium salt (cyclam = 1,4,8,11-tetraazacyclotetradecane)
Davies, PJ
Taylor, MR
Wainwright, KP
[J]. CHEMICAL COMMUNICATIONS, 1998, (07) : 827 - 828
[3] Engel R., 1992, HDB ORGANOPHOSPHORUS
[4] EXCITON COUPLING IN PORPHYRIN DIMERS
HUNTER, CA
SANDERS, JKM
STONE, AJ
[J]. CHEMICAL PHYSICS, 1989, 133 (03) : 395 - 404
[5] ACTIVATION OF DIHYDROGEN BY RUTHENIUM(II)-CHELATING PHOSPHINE COMPLEXES, AND ACTIVATION OF DIOXYGEN BY RUTHENIUM(II) PORPHYRIN COMPLEXES - AN UPDATE
JAMES, BR
PACHECO, A
RETTIG, SJ
THORBURN, IS
BALL, RG
IBERS, JA
[J]. JOURNAL OF MOLECULAR CATALYSIS, 1987, 41 (1-2): : 147 - 161
[6] Assembly of dynamic heterometallic oligoporphyrins using cooperative zinc-nitrogen, ruthenium-nitrogen, and tin-oxygen coordination
Kim, HJ
Bampos, N
Sanders, JKM
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (35) : 8120 - 8121
[7] KIMURA E, 1996, COMPREHENSIVE SUPRAM, V10, P429
[8] A NEW EFFICIENT PREPARATION OF POLYFUNCTIONAL PHOSPHINES USING ZINC ORGANOMETALLICS
LANGER, F
KNOCHEL, P
[J]. TETRAHEDRON LETTERS, 1995, 36 (26) : 4591 - 4594
[9] PREPARATION, CHARACTERIZATION AND REACTION OF THE FIRST DIOXORUTHENIUM(VI) COMPLEXES OF CHIRAL PICKET-FENCE PORPHYRINS
LEMAUX, P
BAHRI, H
SIMONNEAUX, G
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (11) : 1287 - 1288
[10] ENANTIOSELECTIVE OXIDATION OF RACEMIC PHOSPHINES WITH CHIRAL OXORUTHENIUM PORPHYRINS AND CRYSTAL-STRUCTURE OF [5,10,15,20-TETRAKIS[O-((2-METHOXY-2-PHENYL-3,3,3-TRIFLUOROPROPANOYL)AMINO)PHENYL]PORPHYRINATO](CARBONYL)(TETRAHYDROFURAN)RUTHENIUM(II) (ALPHA,BETA,ALPHA,BETA, ISOMER)
LEMAUX, P
BAHRI, H
SIMONNEAUX, G
TOUPET, L
[J]. INORGANIC CHEMISTRY, 1995, 34 (18) : 4691 - 4697

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