Phosphine-substituted porphyrins as supramolecular building blocks

被引：38

作者：

Darling, SL ^{[1
]}

Stulz, E ^{[1
]}

Feeder, N ^{[1
]}

Bampos, N ^{[1
]}

Sanders, JKM ^{[1
]}

机构：

[1] Univ Cambridge, Cambridge Ctr Mol Recognit, Chem Lab, Cambridge CB2 1EW, England

来源：

NEW JOURNAL OF CHEMISTRY | 2000年 / 24卷 / 05期

关键词：

D O I：

10.1039/b000482k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A route to alkyne-phosphine-substituted metalloporphyrins is presented. The X-ray structure of the methanol adduct of a diphenylphosphine Zn(II) porphyrin reveals solid state dimerisation accompanied by proton transfer from coordinated methanol to phosphine in a process reminiscent of carbonic anhydrase, The ability of the phosphine-substituted porphyrins to form non-covalent arrays with a Ru(II) porphyrin was explored using H-1/P-31 NMR and UV/vis spectroscopy as well as MALDI-TOF mass spectrometry.

引用

页码：261 / 264

页数：4

共 19 条

[1] PREPARATION AND CHARACTERIZATION OF SOME RUTHENIUM(II) PORPHYRINS CONTAINING TERTIARY PHOSPHINE AXIAL LIGANDS, INCLUDING THE CRYSTAL-STRUCTURE OF (OCTAETHYLPORPHINATO)BIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II) [J].

ARIEL, S ;

DOLPHIN, D ;

DOMAZETIS, G ;

JAMES, BR ;

LEUNG, TW ;

RETTIG, SJ ;

TROTTER, J ;

WILLIAMS, GM .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1984, 62 (04) :755-762

[2] Formation of 1,11-bis(pendant donor)-cyclam derivatives via the formamidinium salt (cyclam = 1,4,8,11-tetraazacyclotetradecane) [J].

Davies, PJ ;

Taylor, MR ;

Wainwright, KP .

CHEMICAL COMMUNICATIONS, 1998, (07) :827-828

[3]

Engel R., 1992, HDB ORGANOPHOSPHORUS

[4] EXCITON COUPLING IN PORPHYRIN DIMERS [J].

HUNTER, CA ;

SANDERS, JKM ;

STONE, AJ .

CHEMICAL PHYSICS, 1989, 133 (03) :395-404

[5] ACTIVATION OF DIHYDROGEN BY RUTHENIUM(II)-CHELATING PHOSPHINE COMPLEXES, AND ACTIVATION OF DIOXYGEN BY RUTHENIUM(II) PORPHYRIN COMPLEXES - AN UPDATE [J].

JAMES, BR ;

PACHECO, A ;

RETTIG, SJ ;

THORBURN, IS ;

BALL, RG ;

IBERS, JA .

JOURNAL OF MOLECULAR CATALYSIS, 1987, 41 (1-2) :147-161

[6] Assembly of dynamic heterometallic oligoporphyrins using cooperative zinc-nitrogen, ruthenium-nitrogen, and tin-oxygen coordination [J].

Kim, HJ ;

Bampos, N ;

Sanders, JKM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (35) :8120-8121

[7]

KIMURA E, 1996, COMPREHENSIVE SUPRAM, V10, P429

[8] A NEW EFFICIENT PREPARATION OF POLYFUNCTIONAL PHOSPHINES USING ZINC ORGANOMETALLICS [J].

LANGER, F ;

KNOCHEL, P .

TETRAHEDRON LETTERS, 1995, 36 (26) :4591-4594

[9] PREPARATION, CHARACTERIZATION AND REACTION OF THE FIRST DIOXORUTHENIUM(VI) COMPLEXES OF CHIRAL PICKET-FENCE PORPHYRINS [J].

LEMAUX, P ;

BAHRI, H ;

SIMONNEAUX, G .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (11) :1287-1288

[10] ENANTIOSELECTIVE OXIDATION OF RACEMIC PHOSPHINES WITH CHIRAL OXORUTHENIUM PORPHYRINS AND CRYSTAL-STRUCTURE OF [5,10,15,20-TETRAKIS[O-((2-METHOXY-2-PHENYL-3,3,3-TRIFLUOROPROPANOYL)AMINO)PHENYL]PORPHYRINATO](CARBONYL)(TETRAHYDROFURAN)RUTHENIUM(II) (ALPHA,BETA,ALPHA,BETA, ISOMER) [J].

LEMAUX, P ;

BAHRI, H ;

SIMONNEAUX, G ;

TOUPET, L .

INORGANIC CHEMISTRY, 1995, 34 (18) :4691-4697

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