Growth and characterization of cyclohexylaminium hydrogen phthalate hemihydrate nonlinear optical single crystals

被引：14

作者：

Gomathi, R. ^{[1
]}

Madeswaran, S. ^{[1
]}

Babu, D. Rajan ^{[1
]}

机构：

[1] VIT Univ, Sch Adv Sci, Dept Phys, Adv Mat Res Ctr, Vellore, Tamil Nadu, India

来源：

JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS | 2017年 / 28卷 / 15期

关键词：

BIS(CYCLOHEXYLAMMONIUM) TEREPHTHALATE; P-TOLUENESULFONATE; MICROHARDNESS; MONOHYDRATE; NETWORKS; BEHAVIOR; ACIDS; BOND;

D O I：

10.1007/s10854-017-6931-5

中图分类号：

TM [电工技术]; TN [电子技术、通信技术];

学科分类号：

0808 ; 0809 ;

摘要：

Organic bulk single crystal of cyclohexylaminium hydrogen phthalate hemihydrate (CYHPH) was grown by slow cooling method using methanol as a solvent. The grown crystal belongs to orthorhombic system with Pbcn space group and it has various functional groups such as NH3 (+), phthalate and a water molecule. The cut off wavelength of CYHPH was found at 307 nm. Thermal analysis affirmed that the CYHPH compound was stable up to 146 A degrees C and completely decomposed at 263 A degrees C. The activation energy at 100 Hz, 1 and 10 KHz was found to be 0.31, 0.141 and 0.142 eV respectively. The grown CYHPH crystal exhibits third order nonlinear optical behavior.

引用

页码：11374 / 11382

页数：9

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