Bis(μ-8-hydroxy-7-iodoquinoline-5-sulfonato-κ3 N,O:O′)bis[triaquazinc(II)]tetrahydrate

被引：17

作者：

Francis, S

Muthiah, PT ^{[1
]}

Bocelli, G

Cantoni, A

机构：

[1] Bharathidasan Univ, Dept Chem, Tiruchirappalli 620024, India

[2] CNR, IMEM, I-43100 Parma, Italy

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2003年 / 59卷

关键词：

D O I：

10.1107/S1600536803001922

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title compound, [Zn-2 (C9H4INO4S)(2) (H2O)(6)].4H(2)O, the coordination geometry around the Zn-II atom is a distorted octahedron, formed by three water molecules, the N and deprotonated O atoms of the quinolinol ring and one of the O atoms of the sulfonate group. In the centrosymmetric binuclear complex, there is a pi-pi-stacking interaction between the quinolinol rings. The water molecules of crystallization play an important role in the hydrogen-bonding patterns of the three-dimensional network.

引用

页码：M87 / M90

页数：4

共 17 条

[1] SIR97:: a new tool for crystal structure determination and refinement [J].