Baeyer-Villiger Oxidation of Cycloalkanones with In Situ Generated Hydrogen Peroxide from Alcohols and Molecular Oxygen Using NHPI as a Key Catalyst

被引：13

作者：

Kamae, Kenichiro

Obora, Yasushi

Ishii, Yasutaka ^{[1
]}

机构：

[1] Kansai Univ, Dept Chem & Mat Engn, Fac Chem Mat & Bioengn, Osaka 5648680, Japan

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 2009年 / 82卷 / 07期

关键词：

KETONES; PLATINUM(II); COMPLEXES;

D O I：

10.1246/bcsj.82.891

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

One-pot Baeyer-Villiger oxidation of cycloalkanones was successfully achieved by allowing them to react with hydrogen peroxide generated in situ from benzhydrol and molecular oxygen assisted by N-hydroxyphthalimide (NHPI) and 2,2'-azobisisobutyronitrile (AIBN). This method provides an alternative synthetic route to lactones from cycloalkanones using sec-alcohols and molecular oxygen assisted by NHPI.

引用

页码：891 / 895

页数：5

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