Dual-mode semisquaraine-based sensor for selective detection of Hg2+ in a micellar medium

被引:173
作者
Avirah, Rekha R. [1 ]
Jyothish, Kuthanapillil [1 ]
Ramaiah, Danaboyina [1 ]
机构
[1] CSIR, Reg Res Lab, Chem Sci & Technol Div, Trivandrum 695019, Kerala, India
关键词
D O I
10.1021/ol062691v
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A novel chemosensor based on semisquaraine dye (SSQ) for selective detection of Hg2+ is described. SSQ is obtained in quantitative yields from the reaction between squaric acid and 6-ethoxy-2-quinaldinium iodide. SSQ in combination with surfactant shows a dual chromogenic and fluorogenic response selectively toward Hg2+ as compared to Li+, Na+, K+, Ag+, Ca2+, Mg2+, Zn2+, Pb2+, Cd2+, Cu2+, and Fe3+ due to the soft acid nature and size of the mercuric ion.
引用
收藏
页码:121 / 124
页数:4
相关论文
共 26 条