Indium-Based Perovskites: A New Class of Near-Room-Temperature Multiferroics

被引:48
作者
Belik, Alexei A. [1 ]
Furubayashi, Takao [2 ]
Matsushita, Yoshitaka [3 ]
Tanaka, Masahiko [3 ]
Hishita, Shunichi [4 ]
Takayama-Muromachi, Eiji [1 ]
机构
[1] Natl Inst Mat Sci, Int Ctr Mat Nanoarchitecton, Tsukuba, Ibaraki 3050044, Japan
[2] Natl Inst Mat Sci, Magnet Mat Ctr, Tsukuba, Ibaraki 3050047, Japan
[3] NIMS Harima Off, Mikazuki, Hyogo 6795148, Japan
[4] Natl Inst Mat Sci, Sensor Mat Ctr, Tsukuba, Ibaraki 3050044, Japan
关键词
high-pressure chemistry; indium magnetic properties; multiferroics; perovskites; AMBIENT-PRESSURE; POLAR OXIDE; THIN-FILM; POLARIZATION; BISMUTH; ZNSNO3;
D O I
10.1002/anie.200902827
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The temperature's rising: New multiferroic perovskites In 1-xMxMO3 with x=0.112-0.176 and M=Fe 0.5Mn0.5 (see picture) were prepared using high-pressure techniques. They have the same structure as BiFeO3 and high Curie temperatures; in addition, they are canted antiferromagnets with Néel temperatures close to room temperature. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:6117 / 6120
页数:4
相关论文
共 25 条
[1]   Ferroelectric-Paraelectric Transition in BiFeO3: Crystal Structure of the Orthorhombic β Phase [J].
Arnold, Donna C. ;
Knight, Kevin S. ;
Morrison, Finlay D. ;
Lightfoot, Philip .
PHYSICAL REVIEW LETTERS, 2009, 102 (02)
[2]   Magnetic and dielectric properties of hexagonal InMnO3 [J].
Belik, Alexei A. ;
Kamba, Stanislav ;
Savinov, Maxim ;
Nuzhnyy, Dmitry ;
Tachibana, Makoto ;
Takayama-Muromachi, Eiji ;
Goian, V. .
PHYSICAL REVIEW B, 2009, 79 (05)
[3]   LINBO3 - EFFICIENT PHASE MATCHABLE NONLINEAR OPTICAL MATERIAL ( UNIAXIAL PIEZOELECTRIC OPTICAL PARAMETRIC EFFECTS E ) [J].
BOYD, GD ;
NASSAU, K ;
MILLER, RC ;
BOND, WL ;
SAVAGE, A .
APPLIED PHYSICS LETTERS, 1964, 5 (11) :234-+
[4]   A pure bismuth a site polar perovskite synthesized at ambient pressure [J].
Bridges, Craig A. ;
Allix, Mathieu ;
Suchomel, Matthew R. ;
Kuang, Xiaojun ;
Sterianou, Iasmi ;
Sinclair, Derek C. ;
Rosseinsky, Matthew J. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (46) :8785-8789
[5]   Physics and Applications of Bismuth Ferrite [J].
Catalan, Gustau ;
Scott, James F. .
ADVANCED MATERIALS, 2009, 21 (24) :2463-2485
[6]   Multiferroic and magnetoelectric materials [J].
Eerenstein, W. ;
Mathur, N. D. ;
Scott, J. F. .
NATURE, 2006, 442 (7104) :759-765
[7]  
Hill NA, 2000, J PHYS CHEM B, V104, P6694, DOI [10.1021/jp000114x, 10.1021/jpc00114x]
[8]   A polar oxide with a large magnetization synthesized at ambient pressure [J].
Hughes, H ;
Allix, MMB ;
Bridges, CA ;
Claridge, JB ;
Kuang, XJ ;
Niu, HJ ;
Taylor, S ;
Song, WH ;
Rosseinsky, MJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (40) :13790-13791
[9]   Electric polarization reversal and memory in a multiferroic material induced by magnetic fields [J].
Hur, N ;
Park, S ;
Sharma, PA ;
Ahn, JS ;
Guha, S ;
Cheong, SW .
NATURE, 2004, 429 (6990) :392-395
[10]   Positive and Negative Magnetodielectric Effects in A-Site Ordered (BiMn3)Mn4O12 Perovskite [J].
Imamura, Naoki ;
Karppinen, Maarit ;
Motohashi, Teruki ;
Fu, Desheng ;
Itoh, Mitsuru ;
Yamauchi, Hisao .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (45) :14948-+