Adsorption and Desorption Equilibria of Nitrogen, Methane, Ethane, and Ethylene on Date-Pit Activated Carbon

被引:30
作者
Al-Muhtaseb, Shaheen A. [1 ]
机构
[1] Qatar Univ, Dept Chem Engn, Doha, Qatar
关键词
AQUEOUS-SOLUTIONS; WATER-ADSORPTION; SURFACE HETEROGENEITY; GAS-ADSORPTION; SIMULATION; REMOVAL; MODEL; HYSTERESIS; RAW;
D O I
10.1021/je900350k
中图分类号
O414.1 [热力学];
学科分类号
摘要
Date pits were Used to produce a highly porous activated carbon. The resulting date-pit activated carbon was used in a volumetric adsorption apparatus to measure the vapor-phase adsorption and desorption of nitrogen, methane, ethane, and ethylene over a wide range of pressure and at temperatures of (30, 45, and 60) degrees C. Being characterized with a relatively high Surface area, the synthesized date-pit activated carbon exhibited a satisfactory capacity for adsorbing the Various tested gases. However, the desorption of these gases exhibited a hysteresis phenomenon, especially at low temperatures. A Langmuir type model was proposed for fitting both the adsorption and the desorption data with hysteresis, and the corresponding isosteric heats of adsorption and desorption were estimated and compared.
引用
收藏
页码:313 / 319
页数:7
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