Synthesis of new chiral N-substituted fused pyrazoles and pyrazolinols.

被引：25

作者：

Popov, SA

Shakirov, MM

Tkachev, AV

DeKimpe, N

机构：

[1] NOVOSIBIRSK ORGAN CHEM INST,NOVOSIBIRSK 630090,RUSSIA

[2] STATE UNIV GHENT,FAC AGR & APPL BIOL SCI,DEPT ORGAN CHEM,B-9000 GHENT,BELGIUM

来源：

TETRAHEDRON | 1997年 / 53卷 / 52期

基金：

俄罗斯基础研究基金会;

关键词：

D O I：

10.1016/S0040-4020(97)10239-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Treatment of beta-diketones and the corresponding beta-enaminoketones, having modified carane (2-ethyl-6,6-dimethylbicyclo[3.1.0]hexane) and p-menthane (3-ethyl-1-isopropylcyclopentane) skeletons, with aryl-and alkylhydrazines results in regioselective formation of N-substituted pyrazoles or stable pyrazolinols depending on the nature of the substituent at the hydrazine nitrogen. (C) 1997 Elsevier Science Ltd.

引用

页码：17735 / 17750

页数：16