Hydrothermal synthesis, crystal structures and magnetic properties of two bimetallic cage cluster vanadate complexes [Co(phen)2]2V4O12 and [Co(2,2′-bipy)2]2V4O12

被引：6

作者：

Liu, CM

Zhang, DQ

Xiong, M

Dai, MQ

Hu, HM

Zhu, DB ^{[1
]}

机构：

[1] Chinese Acad Sci, Inst Chem, Organ Solids Lab, Ctr Mol Sci, Beijing 100080, Peoples R China

[2] China Univ Geosci, Xray Lab, Beijing 100083, Peoples R China

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2002年 / 55卷 / 11期

关键词：

hydrothermal synthesis; cobalt; cluster; crystal structure; polyoxovanadium; magnetic properties;

D O I：

10.1080/0095897021000036640

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two new bimetallic cluster complexes, [Co(phen)(2)](2)V4O12 1 (phen = phenanthroline) and [Co(2,2'-bipy)(2)](2)V4O12 2 (2,2'-bipy = 2,2'-bipyridine), have been synthesized hydrothermally. X-ray crystallography reveals that both 1 and 2 possess a similar metal cage cluster core, Co2V4O12. Magnetic studies of I and 2 indicate that both the complexes exhibit antiferromagnetic interactions between the cobalt(II) ions.

引用

页码：1327 / 1335

页数：9

共 22 条

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