Structure determination of [tetraethylammonium]-[(1,3-dithiole-2-one-4,5-dithiolato)diphenyl(thiocyanato-N)stannate]

被引：3

作者：

Chohan, ZH ^{[1
]}

Cox, PJ ^{[1
]}

Wardell, JL ^{[1
]}

机构：

[1] ROBERT GORDON UNIV,SCH PHARM,ABERDEEN AB10 1FR,SCOTLAND

来源：

JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 1997年 / 27卷 / 02期

关键词：

organometallic; complex; crystal structure;

D O I：

10.1007/BF02575907

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound (3) has been synthesised and its molecular structure has been elucidated by single crystal X-ray diffraction. Refinement of the complex in space group P2(1)/c with a = 11.535(4), b = 9.831(2), c = 25.217(1) and beta = 94.23(5)degrees converged at R = 0.064. The geometry at the tin center in the anion is trigonal bipyramidal, with the thiocyanato N atom and a dithiolato S atom in the axial sites. The tetraethylammonium cation exhibits normal geometry.

引用

页码：137 / 140

页数：4

共 13 条

[1] SIR92 - a program for automatic solution of crystal structures by direct methods [J].

ALTOMARE, A ;

CASCARANO, G ;

GIACOVAZZO, G ;

GUAGLIARDI, A ;

BURLA, MC ;

POLIDORI, G ;

CAMALLI, M .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1994, 27 :435-435

[2] Preparations and crystal structures of Sn(CH(2)CH(2)CO(2)Me)(2)(C3S5) and [Q][Sn(CH(2)CH(2)CO(2)Me)(C3S5)(2)] (Q=NEt(4) or 1,4-dimethylpyridinium, C3S5=4,5-disulfanyl-1,3-dithiole-2-thionate) [J].

Buchanan, H ;

Howie, RA ;

Khan, A ;

Spencer, GM ;

Wardell, JL ;

Aupers, JH .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1996, (04) :541-548

[3]

CHOHAN ZH, 1997, IN PRESS POLYHEDRON

[4] Tetraethylammonium bis(isothiocyanato)-triphenylstannate [J].

Cox, PJ ;

Wardell, JL .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1996, 52 :317-319

[5] A DIMERIC CALCIUM SILOXIDE LIGHTLY STABILIZED BY AMMONIA LIGANDS [J].

DARR, JA ;

DRAKE, SR ;

HURSTHOUSE, MB ;

MALIK, KMA .

INORGANIC CHEMISTRY, 1993, 32 (25) :5704-5708

[6]

DOIDGEHARRISON SMS, 1991, J ORGANOMET CHEM, P414

[7] Diorganotin 1,3-dithiole-2-thione-4,5-dithiolate compounds, R(2)Sn(dmit): The crystal structure of MePhSn(dmit) [J].

DoidgeHarrison, SMSV ;

Irvine, JTS ;

Khan, A ;

Spencer, GM ;

Wardell, JL ;

Aupers, JH .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1996, 516 (1-2) :199-205

[8]

DOIDGEHARRISON SMSV, 1992, J ORGANOMET CHEM, V436, P23, DOI 10.1016/0022-328X(92)85023-P

[9]

KARAULOV AI, 1992, ABSMAD PROGRAM FAST

[10]

PFLUGRATH JW, 1989, MADNES VERSION 11

← 1 2 →