Facile synthesis of Pd nanostructures with enhanced electrocatalytic performance for ethanol oxidation by a bio-based method

被引:8
作者
Pang, Guigui [1 ]
Sun, Muxue [1 ]
Liu, Peng [1 ]
Hou, Li [1 ]
Gao, Faming [1 ]
机构
[1] Yanshan Univ, Dept Appl Chem, Key Lab Appl Chem, Qinhuangdao 066004, Peoples R China
基金
中国博士后科学基金; 中国国家自然科学基金;
关键词
WALLED CARBON NANOTUBES; ONE-POT SYNTHESIS; CATALYTIC-ACTIVITY; NANOWIRE ARRAYS; ANODIC CATALYST; NANOPARTICLES; METHANOL; ELECTROOXIDATION; NETWORKS;
D O I
10.1039/c6ra00560h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A facile method was developed for the controlled synthesis of well-defined Pd nanoparticles and nanowires, with the assistance of polyhedrin as a growth-directing agent. The concentration of polyhedrin plays a key role in the final morphology. The cyclic voltammetry and current-time tests demonstrate that the Pd samples show vastly superior electrocatalytic properties compared to the commercial Pd/C catalysts. Moreover, the Pd supported by carbon black or multi-wall carbon nanotube exhibits significantly enhanced electrocatalytic activity toward ethanol oxidation, indicating a great potential for application in fuel cells.
引用
收藏
页码:19734 / 19741
页数:8
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