Novel deep eutectic solvent-functionalized carbon nanotubes adsorbent for mercury removal from water

被引：82

作者：

AlOmar, Mohamed Khalid ^{[1
,2
]}

Alsaadi, Mohammed Abdulhakim ^{[2
,3
,4
]}

Jassam, Taha M. ^{[5
]}

Akib, Shatirah ^{[6
]}

Hashim, Mohd Ali ^{[2
,7
]}

机构：

[1] Univ Malaya, Dept Civil Engn, Kuala Lumpur 50603, Malaysia

[2] Univ Malaya, Ctr Ion Liquids, Kuala Lumpur 50603, Malaysia

[3] Univ Malaya, NANOCAT, Nanotechnol & Catalysis Res Ctr, IPS Bldg, Kuala Lumpur 50603, Malaysia

[4] Univ Nizwa, Natl Chair Mat Sci & Met, Nizwa, Oman

[5] UCSI Univ, Fac Engn Technol & Built Environm, Civil Engn Dept, Kuala Lumpur 56000, Malaysia

[6] Heriot Watt Univ Malaysia, EGIS, Sch Energy Geosci Infrastruct & Soc, Putrajaya 62200, Malaysia

[7] Univ Malaya, Dept Chem Engn, Kuala Lumpur 50603, Malaysia

来源：

JOURNAL OF COLLOID AND INTERFACE SCIENCE | 2017年 / 497卷

关键词：

Deep eutectic solvents; Carbon nanotubes; Functionalization; Mercury; Adsorption; SHAPE-CONTROLLED SYNTHESIS; HIGH-INDEX FACETS; CHOLINE CHLORIDE; AQUEOUS-SOLUTION; PHYSICAL-PROPERTIES; CATALYTIC-ACTIVITY; IONIC LIQUIDS; ADSORPTION; NANOPARTICLES; CHEMISTRY;

D O I：

10.1016/j.jcis.2017.03.014

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Due to the interestingly tolerated physicochemical properties of deep eutectic solvents (DES5), they are currently in the process of becoming widely used in many fields of science. Herein, we present a novel Hg2+ adsorbent that is based on carbon nanotubes (CNTs) functionalized by DESs. A DES formed from tetra-n-butyl ammonium bromide (TBAB) and glycerol (Gly) was used as a functionalization agent for CNTs. This novel adsorbent was characterized using Raman spectroscopy, Fourier transform infrared (FTIR) spectroscopy, XRD, FESEM, EDX, BET surface area, and Zeta potential. Later, Hg2+ adsorption conditions were optimized using response surface methodology (RSM). A pseudo-second order model accurately described the adsorption of Hg2+. The Langmuir and Freundlich isotherm models described the absorption of Hg2+ on the novel adsorbent with acceptable accuracy. The maximum adsorption capacity was found to be 177.76 mg/g. (C) 2017 Elsevier Inc. All rights

引用

页码：413 / 421

页数：9

共 64 条

[1] The electrodeposition of silver composites using deep eutectic solvents [J].

Abbott, Andrew P. ;

El Ttaib, Khalid ;

Frisch, Gero ;

Ryder, Karl S. ;

Weston, David .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2012, 14 (07) :2443-2449

[2] Electrodeposition of copper composites from deep eutectic solvents based on choline chloride [J].

Abbott, Andrew P. ;

El Ttaib, Khalid ;

Frisch, Gero ;

McKenzie, Katy J. ;

Ryder, Karl S. .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2009, 11 (21) :4269-4277

[3] Deep eutectic solvents formed between choline chloride and carboxylic acids: Versatile alternatives to ionic liquids [J].

Abbott, AP ;

Boothby, D ;

Capper, G ;

Davies, DL ;

Rasheed, RK .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (29) :9142-9147

[4] Novel solvent properties of choline chloride/urea mixtures [J].

Abbott, AP ;

Capper, G ;

Davies, DL ;

Rasheed, RK ;

Tambyrajah, V .

CHEMICAL COMMUNICATIONS, 2003, (01) :70-71

[5] Purification, cutting, and sidewall functionalization of multiwalled carbon nanotubes using potassium permanganate solutions [J].

Aitchison, Tony J. ;

Ginic-Markovic, Milena ;

Matisons, Janis G. ;

Simon, George P. ;

Fredericks, Peter M. .

JOURNAL OF PHYSICAL CHEMISTRY C, 2007, 111 (06) :2440-2446

[6] Lead Sorption by Carbon Nanofibers Grown on Powdered Activated Carbon - Kinetics and Equilibrium [J].

Al Mamun, Abdullah ;

Ahmed, Yehya M. ;

AlKhatib, Ma'an Fahmi R. ;

Jameel, Ahmad Tariq ;

AlSaadit, Mohammed Abdul Hakeem Abdul Rahman .

NANO, 2015, 10 (02)

[7] New Generation Adsorbents for Water Treatment [J].

Ali, Imran .

CHEMICAL REVIEWS, 2012, 112 (10) :5073-5091

[8] Allyl triphenyl phosphonium bromide based DES-functionalized carbon nanotubes for the removal of mercury from water [J].

AlOmar, Mohamed Khalid ;

Alsaadi, Mohammed Abdulhakim ;

Hayyan, Maan ;

Akib, Shatirah ;

Ibrahim, Muhammad ;

Hashim, Mohd Ali .

CHEMOSPHERE, 2017, 167 :44-52

[9] Lead removal from water by choline chloride based deep eutectic solvents functionalized carbon nanotubes [J].

AlOmar, Mohamed Khalid ;

Alsaadi, Mohammed Abdulhakim ;

Hayyan, Maan ;

Akib, Shatirah ;

Ibrahim, Rusul Khaleel ;

Hashim, Mohd Ali .

JOURNAL OF MOLECULAR LIQUIDS, 2016, 222 :883-894

[10] Functionalization of CNTs surface with phosphonuim based deep eutectic solvents for arsenic removal from water [J].

AlOmar, Mohamed Khalid ;

Alsaadi, Mohammed Abdulhakim ;

Hayyan, Maan ;

Akib, Shatirah ;

Hashim, Mohd Ali .

APPLIED SURFACE SCIENCE, 2016, 389 :216-226

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