Characterization of the low temperature firing BaO-B2O3-SiO2 glass:: The effect of BaO content

被引:38
作者
Lim, Eun-Sub [1 ]
Kim, Byung-Sook [1 ]
Lee, Joon-Hyung [1 ]
Kim, Jeong-Joo [1 ]
机构
[1] Kyungpook Natl Univ, Dept Inorgan Mat Engn, Taegu 702701, South Korea
关键词
glass; borate anomaly; thermal properties; dielectric properties; NMR;
D O I
10.1016/j.jeurceramsoc.2006.04.014
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
In the low temperature sinterable glass system of BaO-B2O3-SiO2, the structural changes of the glasses and the resultant changes in the properties of the glasses were examined as a function of BaO content. B-11 MAS-NMR analysis was conducted in order to examine the coordination number of borons in the glass. It showed that the amount of O-4 was greatest at 35 mol% of BaO. The glass transition temperature, hardness, thermal expansion coefficient and dielectric constant of the glasses were examined and the results were explained on the basis of the structural change. (c) 2006 Elsevier Ltd. All rights reserved.
引用
收藏
页码:825 / 829
页数:5
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