A mild hydration of nitriles catalysed by copper(II) acetate

被引：66
作者：
Marce, Patricia [1 ]
Lynch, James [1 ]
Blacker, A. John [2 ]
Williams, Jonathan M. J. [1 ]
机构：
[1] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England
[2] Univ Leeds, Sch Chem, Inst Proc Res & Dev, Leeds LS2 9JT, W Yorkshire, England
来源：
CHEMICAL COMMUNICATIONS | 2016年 / 52卷 / 07期
基金：
英国工程与自然科学研究理事会;
关键词：
SELECTIVE HYDRATION; PRIMARY AMIDES; ARENE-RUTHENIUM(II) COMPLEXES; CYANOHYDRIN HYDRATION; AQUEOUS-MEDIUM; WATER; EFFICIENT; CONVERSION; ORGANONITRILES; LIGANDS;
D O I：
10.1039/c5cc08714g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A simple, mild and general procedure for the hydration of nitriles to amides using copper as catalyst and promoted by N, N-diethyl-hydroxylamine is described. The reaction can be conducted in water at low temperature in short reaction times. This new procedure allows amides to be obtained from a wide range of substrates in excellent yields.
引用
收藏
页码：1436 / 1438
页数：3
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