Effects of bentonite content on the corrosion evolution of low carbon steel in simulated geological disposal environment

被引：9

作者：

Wei, Xin ^{[1
]}

Dong, Junhua ^{[1
]}

Chen, Nan ^{[2
]}

Yadav, Amar Prasad ^{[2
,3
]}

Ren, Qiying ^{[2
]}

Wei, Jie ^{[1
]}

Wang, Changgang ^{[1
]}

Ma, Rongyao ^{[1
]}

Ke, Wei ^{[2
]}

机构：

[1] Chinese Acad Sci, Shenyang Natl Lab Mat Sci, Inst Met Res, Shenyang 110016, Peoples R China

[2] Chinese Acad Sci, Environm Corros Ctr Mat, Inst Met Res, Shenyang 110016, Peoples R China

[3] Tribhuvan Univ, Cent Dept Chem, Kathmandu, Nepal

来源：

JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY | 2021年 / 66卷

基金：

中国国家自然科学基金;

关键词：

Low carbon steel; Bentonite; Electrochemical measurements; Corrosion products; Corrosion evolution; LEVEL RADIOACTIVE-WASTE; LOW-ALLOY STEEL; SWELLING CHARACTERISTICS; COMPACTED BENTONITE; DISSOLVED-OXYGEN; IONIC-STRENGTH; BEHAVIOR; IRON; PH; TEMPERATURE;

D O I：

10.1016/j.jmst.2020.04.071

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The effects of bentonite content on the corrosion behavior of low carbon steel in 5 mM NaHCO3 + 1 mM NaCl + 1 mM Na2SO4 solution were investigated by electrochemical measurements combined with X-ray diffraction (XRD) and scanning electron microscopy (SEM). In the initial immersion stage, the cathodic process of low carbon steel corrosion was dominated by the reduction of dissolved oxygen, while it transformed to the reduction of ferric corrosion products with the immersion time. The presence of bentonite colloids could suppress the cathodic reduction of oxygen due to their barrier effect on the diffusion of oxygen. However, the barrier performance of bentonite layer was gradually deteriorated due to the coagulation and separation of bentonite colloids caused by the charge neutralization of iron corrosion products dissolved from the steel substrate. More bentonite colloids could maintain the barrier effect for a long time before it was deteriorated by the accumulation of corrosion products. Conversely, it could lose the performance completely, and the corrosion behavior of low carbon steel reverted to the same as that in the blank solution. (C) 2021 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology.

引用

页码：46 / 56

页数：11