Structural Trends in Coordination Polymers Containing Perfluorinated Dicarboxylates and 4,4′-Bipyridine

被引：22

作者：

Hulvey, Zeric ^{[2
]}

Ayala, Elizabeth ^{[2
]}

Cheetham, Anthony K. ^{[1
]}

机构：

[1] Univ Cambridge, Dept Mat Sci & Met, Cambridge CB2 3QZ, England

[2] Univ Calif Santa Barbara, Mat Res Lab, Santa Barbara, CA 93106 USA

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2009年 / 635卷 / 12期

基金：

美国国家科学基金会; 欧洲研究理事会;

关键词：

Polymers; Cobalt; Zinc; Perfluorinated ligands; Structure elucidation; 4,4 '-bipyridine; METAL-ORGANIC FRAMEWORKS; HYDROGEN STORAGE; CRYSTAL-STRUCTURES; COMPLEXES; SORPTION; SERIES; NET;

D O I：

10.1002/zaac.200900312

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new family of coordination polymers has been synthesized using cobalt or zinc, 4,4'-bipyridine (4,4'-bpy), and the perfluorinated dicarboxylatcs tetrafluoroterephthalate (tftpa), tetrafluorophthalate (tfpha), tetrafluoroisophthalate (tfipa), and tetra fluorosuccinate (tfsuc). These materials form under similar conditions and all display similar octahedral metal coordination environments despite significant differences in their Structures. The compounds M(4,4'-bpy)(tftpa)-(H2O)(2) (M = Co, Zn) (1) and M(4,4'-bpy)(tfpha)(H2O)(2) (M = Co, Zn) (2) are two-dimensional layered structures, whereas Co(4,4'-bpy)-(tfsuc)(H2O)(2) (3) and M(4,4'-bpy)(tfipa)(H2O)(2) (M = Co, Zn) (4) display three-dimensional connectivity built up from two types of interconnected chains.

引用

页码：1753 / 1757

页数：5

共 33 条

[1] Silver coodination polymers with flexible ligands.: Syntheses, crystal structures, and effect of the counteranion and the solvent on the structure of complexes [AgL1X]∞ of the bis(phenylthio)methane ligand L1 with silver(I) salts, X = ClO4-, BF4-, CF3COO-, CF3SO3-, CF3CF2CF2COO-, and -OOCCF2CF2COO-
Awaleh, MO
Badia, A
Brisse, F
[J]. CRYSTAL GROWTH & DESIGN, 2005, 5 (05) : 1897 - 1906
[2] Zinc dicarboxylate polymers and dimers: thiourea substitution as a tool in supramolecular synthesis
Burke, NJ
Burrows, AD
Donovan, AS
Harrington, RW
Mahon, MF
Price, CE
[J]. DALTON TRANSACTIONS, 2003, (20) : 3840 - 3849
[3] Structural diversity and chemical trends in hybrid inorganic-organic framework materials
Cheetham, Anthony K.
Rao, C. N. R.
Feller, Russell K.
[J]. CHEMICAL COMMUNICATIONS, 2006, (46) : 4780 - 4795
[4] Enhanced near-infrared-luminescence in an erbium tetrafluoroterephthalate framework
Chen, Banglin
Yang, Yu
Zapata, Fatima
Qian, Guodong
Luo, Yongshi
Zhang, Jiahua
Lobkovsky, Emil B.
[J]. INORGANIC CHEMISTRY, 2006, 45 (22) : 8882 - 8886
[5] Synthesis, X-ray crystal structures, and gas sorption properties of pillared square grid nets based on paddle-wheel motifs: Implications for hydrogen storage in porous materials
Chun, H
Dybtsev, DN
Kim, H
Kim, K
[J]. CHEMISTRY-A EUROPEAN JOURNAL, 2005, 11 (12) : 3521 - 3529
[6] Hydrogen storage in metal-organic frameworks
Collins, David J.
Zhou, Hong-Cai
[J]. JOURNAL OF MATERIALS CHEMISTRY, 2007, 17 (30) : 3154 - 3160
[7] Hydrogen storage in microporous metal-organic frameworks with exposed metal sites
Dinca, Mircea
Long, Jeffrey R.
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (36) : 6766 - 6779
[8] Molecular tectonics of mixed-ligand metal-organic frameworks: Positional isomeric effect, metal-directed assembly, and structural diversification
Du, Miao
Jiang, Xiu-Juan
Zhao, Xiao-Jun
[J]. INORGANIC CHEMISTRY, 2007, 46 (10) : 3984 - 3995
[9] Polytypism, homochirality, interpenetration, and hydrogen-bonding in transition metal (Mn(II), Ni(II), Cu(II), Zn(II)) 5-hydroxyisophthalate coordination polymers containing 4,4′-bipyridyl
Feller, Russell K.
Cheetham, Anthony K.
[J]. DALTON TRANSACTIONS, 2008, (15) : 2034 - 2042
[10] A rare-earth MOF series:: Fascinating structure, efficient light emitters, and promising catalysts
Gandara, F.
de Andres, A.
Gomez-Lor, B.
Gutierrez-Puebla, E.
Iglesias, M.
Monge, M. A.
Proserpio, D. M.
Snejko, N.
[J]. CRYSTAL GROWTH & DESIGN, 2008, 8 (02) : 378 - 380

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