Bis-phosphine allene ligand: coordination chemistry and preliminary applications in catalysis

被引：20
作者：
Vanitcha, Avassaya [1 ]
Damelincourt, Cecilia [1 ]
Gontard, Geoffrey [1 ]
Vanthuyne, Nicolas [2 ]
Mouries-Mansuy, Virginie [1 ]
Fensterbank, Louis [1 ]
机构：
[1] Univ Paris 06, CNRS, Inst Parisien Chim Mol, Sorbonne Univ,UMR 8232, 4 Pl Jussieu,C-229, F-75005 Paris, France
[2] Aix Marseille Univ, CNRS, Cent Marseille, iSm2 UMR 7313, F-13397 Marseille, France
来源：
CHEMICAL COMMUNICATIONS | 2016年 / 52卷 / 41期
关键词：
RAY CRYSTAL-STRUCTURE; ENANTIOSELECTIVE SYNTHESIS; GOLD(I) COMPLEXES; DONOR PROPERTIES; ACTIVATION; CYCLOADDITIONS; RESOLUTION; SILVER; ENANTIOMERS; DERIVATIVES;
D O I：
10.1039/c6cc02316a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A 1,3-bis-diphenylphosphine allene can give rise to new coordination complexes with palladium, platinum and gold metals. These complexes were fully characterized by NMR, HRMS and X-ray diffraction analysis. For gold(I), the corresponding dinuclear complex has been used in a series of diagnostic catalytic reactions and gave promising preliminary results in asymmetric catalysis.
引用
收藏
页码：6785 / 6788
页数：4
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