An Expeditious Entry to Benzylic and Allylic Sulfones through Byproduct-Catalyzed Reaction of Alcohols with Sulfinyl Chlorides

被引：73

作者：

Li, Hai-Hua ^{[1
]}

Dong, De-Jun ^{[1
]}

Jin, Yin-Huan ^{[1
]}

Tian, Shi-Kai ^{[1
]}

机构：

[1] Univ Sci & Technol China, Dept Chem, Hefei 230026, Anhui, Peoples R China

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2009年 / 74卷 / 24期

基金：

中国国家自然科学基金;

关键词：

BAYLIS-HILLMAN ADDUCTS; REARRANGEMENT; SUBSTITUTION; ESTERS; SULFOXIDES; ACID; 2-HYDROXYDIARYL; SULFONAMIDES; DERIVATIVES; ALKYLATION;

D O I：

10.1021/jo901974h

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In the absence of external catalysts and additives, a broad range of benzylic and allylic alcohols react with various sulfinyl chlorides to afford structurally diversified benzylic and allylic sulfones in moderate to excellent yields, and importantly, a catalysis with byproduct HCl is involved in this new protocol for sulfone synthesis.

引用

页码：9501 / 9504

页数：4

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