Supramolecular Polymers and Chromonic Mesophases Self-Organized from Phosphorescent Cationic Organoplatinum(II) Complexes in Water

被引：177
|
作者：
Lu, Wei [1 ,2 ]
Chen, Yong [1 ,2 ]
Roy, V. A. L. [1 ,2 ]
Chui, Stephen Sin-Yin [1 ,2 ]
Che, Chi-Ming [1 ,2 ]
机构：
[1] Univ Hong Kong, Dept Chem, Hong Kong, Hong Kong, Peoples R China
[2] Univ Hong Kong, HKU CAS Joint Lab New Mat, Hong Kong, Hong Kong, Peoples R China
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 41期
关键词：
liquid crystals; luminescence; metal-metal interactions; platinum; supramolecular chemistry; FIELD-EFFECT TRANSISTORS; CYCLOMETALATED PLATINUM(II) COMPLEXES; LIQUID-CRYSTALS; PI-PI; PHTHALOCYANINES; SPECTROSCOPY; NANOWIRES; EMISSION; SOLVENTS; LIGANDS;
D O I：
10.1002/anie.200903109
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Soft matter with a hard core: Through PtII PtII and hydrophobic interactions, planar organoplatinum(II) cations with chloride or sulfate as counterions self-organize themselves in water into red-emissive, chromonic, and viscoelastic mesophases from which aligned films and discrete uniaxial microfibers with cofacial molecular orientations can be readily prepared. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：7621 / 7625
页数：5
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