Synthesis of MIL-53(Fe) Metal-Organic Framework Material and Its Application as a Catalyst for Fenton-Type Oxidation of Organic Pollutants

被引:27
|
作者
Pham Dinh Du [1 ]
Pham Ngoc Hoai [1 ]
机构
[1] Thu Dau Mot Univ, Thu Dau Mot 75000, Vietnam
关键词
Carboxylation - High resolution transmission electron microscopy - Crystallinity - Scanning electron microscopy - Crystal structure - Oxidation - Catalysts - Fourier transform infrared spectroscopy - X ray photoelectron spectroscopy - Iron compounds - Organic pollutants - Photocatalytic activity - Aromatic compounds - Metal-Organic Frameworks - Organic solvents - Dimethylformamide - Organic polymers;
D O I
10.1155/2021/5540344
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The iron (III) benzene dicarboxylate metal-organic framework material (MIL-53(Fe)) was synthesized with either the solvent-thermal or hydrothermal method under different conditions. The influence of the type of solvents, molar ratio of precursors and solvent, temperature, and reaction time on the structure of MIL-53(Fe) was investigated. The material was characterized by using X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HR-TEM), X-ray photoelectron spectroscopy (XPS), and N-2 adsorption/desorption isotherm. The MIL-53(Fe) structure formed in N ', N-dimethylformamide (DMF) and methanol (MeOH) but not in water. In DMF, the molar ratio of precursors and solvent, temperature, and reaction time had a significant effect on the crystal structure of MIL-53(Fe). Under optimal conditions, MIL-53(Fe) has high crystallinity and a large specific surface area (SBET = 88.2 m(2)/g). The obtained MIL-53(Fe) could serve as a potential heterogeneous catalyst to oxidize phenol (PhN), rhodamine B (RhB), and methylene blue (MtB) in the Fenton-like reaction system at the different solution pHs.
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页数:13
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