Chan-Lam-Type C-N Cross-Coupling Reactions under Base-and Ligand-Free CuI-Zeolite Catalysis

被引：24

作者：

Garnier, Tony ^{[1
]}

Sakly, Randa ^{[1
,2
]}

Danel, Mathieu ^{[1
]}

Chassaing, Stefan ^{[1
]}

Pale, Patrick ^{[3
]}

机构：

[1] Univ Toulouse, Inst Technol Avancees Sci Vivant ITAV, CNRS, UPS, 1 Pl Pierre Potier, F-31106 Toulouse 1, France

[2] Univ Monastir, Fac Sci Monastir, LCOHPNR, Monastir, Tunisia

[3] Univ Strasbourg, CNRS, Lab Synthese React Organ & Catalyse LASYROC, Inst Chim,UMR7177, 4 Rue Blaise Pascal, F-67070 Strasbourg, France

来源：

SYNTHESIS-STUTTGART | 2017年 / 49卷 / 06期

关键词：

copper; zeolites; heterogeneous catalysis; cross-coupling; Chan-Lam reaction; C-N bond formation; ARYLBORONIC ACIDS; CLICK CHEMISTRY; COPPER; ARYLATION; PHENYL; AMINES;

D O I：

10.1055/s-0036-1588652

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Various representative copper(I)-exchanged zeolites were investigated for their catalytic potential in Chan-Lam cross-coupling reactions. Cu-I-USY appeared as the best catalyst and proved to efficiently promote C-N cross-coupling processes under attractive, simple, and practical conditions, namely refluxing in methanol under air and without any base.

引用

页码：1223 / 1230

页数：8

共 52 条

[1] 'Click chemistry' in CuI-zeolites:: a convenient access to glycoconjugates [J].