Silanol Mediated π-Assembly of Extended N-Heterocycles

被引：3
作者：
Krekic, Kristijan [1 ,2 ]
Hurkes, Natascha F. [1 ,2 ]
Bruhn, Clemens [1 ,2 ]
Belaj, Ferdinand [3 ,4 ]
Pietschnig, Rudolf [1 ,2 ]
机构：
[1] Univ Kassel, Inst Chem, Heinrich Plett Str 40, D-34132 Kassel, Germany
[2] Univ Kassel, CINSaT, Heinrich Plett Str 40, D-34132 Kassel, Germany
[3] Karl Franzens Univ Graz, Inst Chem, Schubertstr 1, A-8010 Graz, Austria
[4] Karl Franzens Univ Graz, NAWI Graz, Schubertstr 1, A-8010 Graz, Austria
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2016年 / 642卷 / 04期
关键词：
Silanol; Hydrogen bonds; pi Stacking; Molecular clip; SILANETRIOL; ACTIVATION; INHIBITORS; CARBONYL; PROGRAM; DRIVEN; BOND;
D O I：
10.1002/zaac.201500816
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Self-assembly of silanetriols with 4,4-bipyridine affords infinite columns of cofacially arranged -stacks as evidenced by X-ray data. Variation of the silanetriol reveals a subtle balance between hydrogen bonding and interactions, which, by proper choice of the substituent, may foster either dominant hydrogen bonding or dominant pi interaction.
引用
收藏
页码：302 / 305
页数：4
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