Silanol Mediated π-Assembly of Extended N-Heterocycles

被引：3

作者：

Krekic, Kristijan ^{[1
,2
]}

Hurkes, Natascha F. ^{[1
,2
]}

Bruhn, Clemens ^{[1
,2
]}

Belaj, Ferdinand ^{[3
,4
]}

Pietschnig, Rudolf ^{[1
,2
]}

机构：

[1] Univ Kassel, Inst Chem, Heinrich Plett Str 40, D-34132 Kassel, Germany

[2] Univ Kassel, CINSaT, Heinrich Plett Str 40, D-34132 Kassel, Germany

[3] Karl Franzens Univ Graz, Inst Chem, Schubertstr 1, A-8010 Graz, Austria

[4] Karl Franzens Univ Graz, NAWI Graz, Schubertstr 1, A-8010 Graz, Austria

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2016年 / 642卷 / 04期

关键词：

Silanol; Hydrogen bonds; pi Stacking; Molecular clip; SILANETRIOL; ACTIVATION; INHIBITORS; CARBONYL; PROGRAM; DRIVEN; BOND;

D O I：

10.1002/zaac.201500816

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Self-assembly of silanetriols with 4,4-bipyridine affords infinite columns of cofacially arranged -stacks as evidenced by X-ray data. Variation of the silanetriol reveals a subtle balance between hydrogen bonding and interactions, which, by proper choice of the substituent, may foster either dominant hydrogen bonding or dominant pi interaction.

引用

页码：302 / 305

页数：4

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