Sulfonic Acid and Ionic Liquid Functionalized Covalent Organic Framework for Efficient Catalysis of the Biginelli Reaction

被引：104
作者：
Yao, Bing-Jian [1 ]
Wu, Wen-Xiu [1 ]
Ding, Luo-Gang [1 ]
Dong, Yu-Bin [1 ]
机构：
[1] Shandong Normal Univ, Minist Educ, Key Lab Mol & Nano Probes,Coll Chem Chem Engn & M, Collaborat Innovat Ctr Functionalized Probes Chem, Jinan 250014, Peoples R China
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2021年 / 86卷 / 03期
关键词：
ONE-POT SYNTHESIS; HIGHLY EFFICIENT; 3,4-DIHYDROPYRIMIDIN-2(1H)-ONES; DIHYDROPYRIMIDINONES; NANOPARTICLES; FACILE;
D O I：
10.1021/acs.joc.0c02423
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A quinoline-linked and ionic liquid-decorated covalent organic framework was prepared by incorporation of a multicomponent Povarov reaction and postsynthetic modification. The imidazolium and sulfonic acid-decorated COF-IM-SO3H can be a highly efficient Bronsted acid catalyst to promote the Biginelli reaction under solvent-free conditions in a heterogeneous way. In addition, a scaled-up Biginelli reaction has been readily realized over a COF-IM-SO3H@chitosan aerogel-based cup reactor.
引用
收藏
页码：3024 / 3032
页数：9
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