Synthesis, Characterization and Antibacterial Activity of Triorganotin(IV) Complexes of 4-Methylphenol

被引：0
作者：
Sharma, Neeraj [1 ]
Kumar, V. [1 ]
Thakur, M. [1 ]
Kumari, M. [1 ]
Chaudhry, S. C. [1 ]
机构：
[1] Himachal Pradesh Univ, Dept Chem, Shimla 171005, Himachal Prades, India
来源：
POLISH JOURNAL OF CHEMISTRY | 2009年 / 83卷 / 12期
关键词：
trialkyl and triaryltinchlorides; 4-methylphenol; spectral studies; antibacterial activity; RAY CRYSTAL-STRUCTURES; DIORGANOTIN(IV) COMPLEXES; SPECTROSCOPIC CHARACTERIZATION; INFRARED-SPECTRA; SCHIFF-BASES; ACID; POLYMERIZATION; DERIVATIVES; CHEMISTRY; C-13;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The triorganotin(IV) complex of composition Ph3Sn(OArMe-4) has been synthesized in good yields by the reaction of Ph3SnCl with Me(3)SiOArMc-4/NaOArMe-4, while complexes of composition Me3Sn(OArMe-4) and n-Bu3Sn(OArMe-4) (where-OArMe-4 = -OC6H4CH3-4) have been obtained from the reaction of Me3SnCl and n-Bu3SnCl with 4-methylphenol in the presence of triethylamine in carbon tetrachloride. The complexes have been characterized by elemental analyses, molar conductance measurements, molecular weight determination and IR, H-1 and C-13 NMR and mass spectral studies. Thermal behaviour of the complexes has been studied by TG and DTA techniques. The organotin(IV) complexes have also been screened for their antibacterial properties and are found to exhibit appreciable activity. The reactions of the complexes with 2-, 3-, 4-cyanopyridines yielded 1:1 adducts as confirmed by physicochemical and IR spectral data.
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页码：2051 / 2065
页数：15
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