Expanding the role of chemistry to produce new amphiphilic polymer (co)networks

被引：78

作者：

Mespouille, Laetitia ^{[1
]}

Hedrick, James L. ^{[2
]}

Dubois, Philippe ^{[1
]}

机构：

[1] Univ Mons, CIRMAP, Lab Polymer & Composite Mat, B-7000 Mons, Belgium

[2] IBM Corp, Almaden Res Ctr, San Jose, CA 95120 USA

来源：

SOFT MATTER | 2009年 / 5卷 / 24期

关键词：

TRANSFER RADICAL POLYMERIZATION; RING-OPENING POLYMERIZATION; FRAGMENTATION CHAIN TRANSFER; POLY(ETHYLENE GLYCOL) MACROMER; CORNEAL IMPLANT APPLICATIONS; END-LINKING PROCESSES; CLICK-CHEMISTRY; SWELLING BEHAVIOR; BLOCK-COPOLYMERS; NETWORK HYDROGELS;

D O I：

10.1039/b910041p

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Preparation of model amphiphilic polymer networks (APNs) using various polymerization mechanisms and/or organic coupling reactions are reviewed. A particular emphasis is made on controlled/"living'' polymerization techniques in their diversities and how they impact on the structure-reactivity relationships. Advantages and limitations of each technique, as well as improvement of final physical/dynamical properties, are thoroughly discussed and compared for some of the mechanisms. Confrontation of experimental data with Flory's theory is also displayed in the particular case of controlled radical polymerization (CRPs) techniques. Synthesis of model APNs by the end-linking process using efficient organic coupling reactions such as Michael-type addition, Huisgen 1,3-dipolar cycloaddition and thiol-ene click reactions are deeply illustrated and discussed.

引用

页码：4878 / 4892

页数：15

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