Effect of alkali metal salts on decomposition of ionic liquid like organic salt

被引:1
|
作者
Jo, Gyeong Cheol [1 ]
Goh, Eun Mee [2 ]
Baek, Seung Wook [3 ]
Cho, Sung June [1 ]
机构
[1] Chonnam Natl Univ, Dept Appl Chem Engn, 77 Yongbong Ro, Kwangju 500757, South Korea
[2] Agcy Def Dev, POB 35, Daejeon 305600, South Korea
[3] Korea Adv Inst Sci & Technol, Sch Mech Aerosp & Syst Engn, Prop & Combust Lab, 373-1 Guseong Dong, Taejon 305701, South Korea
关键词
Ionic salts; Hypergolic; Catalytic decomposition; Alkali metal additive; IRIDIUM CATALYST; THERMAL-DECOMPOSITION; HYDRAZINE HYDRATE; PROPELLANT; COMBUSTION; FUELS; HAN; CHEMISTRY; TOXICITY; THRUSTER;
D O I
10.1007/s11164-015-2315-8
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
N (1),N (1),N (2),N (2)-tetramethylethane-1,2-diamine-based ionic salts (TMEDA), N (1),N (1),N (1),N (2),N (2),N (2)-hexamethylethane-1,2-diaminium dicyanamide (HMEDA-(DCA)(2)) were prepared following the quaternization and subsequent ion exchange. The chemical structure of the HMEDA-(DCA)(2) was confirmed using C-13 NMR spectrum and elemental analysis. The corresponding viscosity of its 60 wt% solution was found to be lower than 5 cP at room temperature, which was critical for propellant application. The ignition delay of 40 wt% HMEDA-(DCA)(2) solution was decreased to 20-30 ms dramatically using alkali metal salts, Li(CH3COO), Mg(CH3COO)(2), and Ca(CH3COO)(2) as a co-catalyst when white fume nitric acid was utilized as an oxidizer.
引用
收藏
页码:201 / 209
页数:9
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