Mixed-Metal MOFs: Unique Opportunities in Metal-Organic Framework (MOF) Functionality and Design

被引：758
作者：
Masoomi, Mohammad Yaser [1 ]
Morsali, Ali [1 ]
Dhakshinamoorthy, Amarajothi [2 ]
Garcia, Hermenegildo [3 ,4 ]
机构：
[1] Tarbiat Modares Univ, Fac Sci, Dept Chem, POB 14155-4838, Tehran, Iran
[2] Madurai Kamaraj Univ, Sch Chem, Madurai 625021, Tamil Nadu, India
[3] Univ Politecn Valencia, Dept Quim, E-46022 Valencia, Spain
[4] Univ Politecn Valencia, Inst Univ Tecnol Quim, CSIC, E-46022 Valencia, Spain
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2019年 / 58卷 / 43期
关键词：
metal-organic frameworks (MOFs); heterogeneous catalysis; mixed-metal MOFs; mixed-valence MOFs; tandem reactions; ORGANOMETALLIC CVD-PRECURSORS; POROUS COORDINATION POLYMER; SINGLE-CRYSTAL; VISIBLE-LIGHT; CATALYTIC-ACTIVITY; MICROPOROUS METAL; SELECTIVE GAS; COLORIMETRIC DETECTION; HYDROGEN ADSORPTION; INCLUSION-COMPOUNDS;
D O I：
10.1002/anie.201902229
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Mixed-metal metal-organic frameworks (MM-MOFs) can be considered to be those MOFs having two different metals anywhere in the structure. Herein we summarize the various strategies for the preparation of MM-MOFs and some of their applications in adsorption, gas separation, and catalysis. It is shown that compared to homometallic MOFs, MM-MOFs bring about the opportunity to take advantage of the complexity and the synergism derived from the presence of different metal ions in the structure of MOFs. This is reflected in a superior performance and even stability of MM-MOFs respect to related single-metal MOFs. Emphasis is made on the use of MM-MOFs as catalysts for tandem reactions.
引用
收藏
页码：15188 / 15205
页数：18
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