Study of ceramic materials in the SrSnO3-NaNbO3 system by X-ray diffraction, dielectric and Raman spectroscopy

被引:19
作者
Aydi, Abdelhedi [1 ]
Khemakhem, Hamadi [1 ]
Simon, Annie [2 ]
Michau, Dominique [2 ]
von der Muehll, Regnault [2 ]
机构
[1] Fac Sci Sfax, Lab Mat Ferroelect, Sfax 3018, Tunisia
[2] Univ Bordeaux, CNRS, ICMCB, F-33608 Pessac, France
关键词
Ceramic; Dielectric; Ferroelectric; Relaxor; Raman and X-ray diffraction; RELAXOR; PEROVSKITE; FERROELECTRICS; LEAD;
D O I
10.1016/j.jallcom.2009.04.097
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Ceramics with composition belonging to the SrSnO3-NaNbO3 system were sintered in the temperature range 1100-1350 degrees C. The symmetry, dielectric properties and Raman spectroscopy were investigated. X-ray diffraction results demonstrate that a region with the cubic or tetragonal phases lies in the composition range x < 0.89 and x >= 0.89, respectively. The thermal behavior of the dielectric permittivity suggests the existence of two phases: cubic-paraelectric and tetragonal-ferroelectric or ferroelectric relaxor. The Raman spectra was recorded at room temperature and their evolution related to the chemical composition. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:356 / 359
页数:4
相关论文
共 23 条
[1]   Structural characterization of nanocrystalline SnO2 by X-ray and Raman spectroscopy [J].
Abello, L ;
Bochu, B ;
Gaskov, A ;
Koudryavtseva, S ;
Lucazeau, G ;
Roumyantseva, M .
JOURNAL OF SOLID STATE CHEMISTRY, 1998, 135 (01) :78-85
[2]   New ferroelectric and relaxor ceramics in the mixed oxide system NaNbO3-BaSnO3 [J].
Aydi, A ;
Khemakhem, H ;
Boudaya, C ;
Von der Mühll, R ;
Simon, A .
SOLID STATE SCIENCES, 2004, 6 (04) :333-337
[3]   X-ray and dielectric studies of ferroelectric or relaxor phases in the Ca1-xNaxSn1-xNbxO3 system [J].
Aydi, A ;
Khemakhem, H ;
Boudaya, C ;
Simon, A ;
Von der Mühll, R .
SOLID STATE SCIENCES, 2005, 7 (03) :249-255
[4]  
Bahri F, 2001, PHYS STATUS SOLIDI A, V184, P459, DOI 10.1002/1521-396X(200104)184:2<459::AID-PSSA459>3.0.CO
[5]  
2-0
[6]   ESDS AND ESTIMATED PROBABLE-ERROR OBTAINED IN RIETVELD REFINEMENTS WITH LOCAL CORRELATIONS [J].
BERAR, JF ;
LELANN, P .
JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1991, 24 :1-5
[7]   CHOICE OF COLLIMATORS FOR A CRYSTAL SPECTROMETER FOR NEUTRON DIFFRACTION [J].
CAGLIOTI, G ;
PAOLETTI, A ;
RICCI, FP .
NUCLEAR INSTRUMENTS & METHODS, 1958, 3 (04) :223-228
[8]   RELAXOR FERROELECTRICS: AN OVERVIEW [J].
Cross, L. Eric .
FERROELECTRICS, 1994, 151 (01) :305-320
[9]   Effects of calcium on the phase transition and the dielectric properties of Sm-modified PbTiO3 ceramics [J].
Dai, SB ;
Juang, YD ;
Hwang, JS ;
Chen, DE ;
Chu, SY .
JOURNAL OF CRYSTAL GROWTH, 2003, 255 (3-4) :298-302
[10]   A Raman and dielectric study of ferroelectric Ba(Ti1-xZrx)O3 ceramics [J].
Farhi, R ;
El Marssi, M ;
Simon, A ;
Ravez, J .
EUROPEAN PHYSICAL JOURNAL B, 1999, 9 (04) :599-604