5-Fluoro-2-(4-iodophenyl)-3-methylsulfinyl-1-benzofuran

被引:5
作者
Choi, Hong Dae [2 ]
Seo, Pil Ja [2 ]
Son, Byeng Wha [1 ]
Lee, Uk [1 ]
机构
[1] Pukyong Natl Univ, Dept Chem, Pusan 608737, South Korea
[2] Dong Eui Univ, Dept Chem, Pusan 614714, South Korea
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2009年 / 65卷
关键词
D O I
10.1107/S1600536809030992
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, C15H10FIO2S, the O atom and the methyl group of the methylsulfinyl substituent lie on opposite sides of the plane through the benzofuran fragment. The 4-iodophenyl ring is rotated out of the benzofuran plane by a dihedral angle of 39.4 (1)degrees. The crystal structure is stabilized by an intermolecular C-H center dot center dot center dot O hydrogen bond and an I center dot center dot center dot O halogen bond [3.055 (2) angstrom]. The crystal structure also exhibits an intermolecular C-H center dot center dot center dot pi interaction between the methyl H atom and the 4-iodophenyl ring of an adjacent benzofuran molecule, and aromatic pi-pi interactions between the benzene rings of neighbouring benzofuran systems [centroid-centroid distance = 3.558 (3) angstrom].
引用
收藏
页码:O2115 / U1693
页数:11
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